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Updated: Jun 17, 2026

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自组装的双烯 Tweezer 均衡通过多响应性属性控制

Johnny Hu1, Jean-Pierre Launay2, Alain Chaumont3

  • 1LSAMM, Institut de Chimie de Strasbourg, CNRS UMR 7177, Université de Strasbourg, 4, rue Blaise Pascal, 67000, Strasbourg, France.

Chemistry (Weinheim an der Bergstrasse, Germany)
|May 23, 2024
PubMed
概括

合成的 bis-acridinium 针可以自组装成 homodimers. pH 和氧化还原变化调节这些平衡,通过外部刺激来控制分子组合.

关键词:
亚克里迪尼是一种.电化学 电化学 电化学交织在一起的二元体.色主义是一种色主义.分子子分子子.

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Woodward–Hoffmann Selection Rules and Microscopic Reversibility01:34

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Electrocyclic reactions, cycloadditions, and sigmatropic rearrangements are concerted pericyclic reactions that proceed via a cyclic transition state. These reactions are stereospecific and regioselective. The stereochemistry of the products depends on the symmetry characteristics of the interacting orbitals and the reaction conditions. Accordingly, pericyclic reactions are classified as either symmetry-allowed or symmetry-forbidden. Woodward and Hoffmann presented the selection criteria for...