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相关概念视频

Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

990
Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
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Metal-Ligand Bonds02:51

Metal-Ligand Bonds

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The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
18.4K
Extraction: Advanced Methods00:56

Extraction: Advanced Methods

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Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
446
Bonding in Metals02:32

Bonding in Metals

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Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
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Synthesis and Characterization of Functionalized Metal-organic Frameworks
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功能性的金属有机液体.

Nattapol Ma1,2, Soracha Kosasang3, Ellan K Berdichevsky4

  • 1International Center for Young Scientists (ICYS), National Institute for Materials Science 1-1 Namiki Tsukuba Ibaraki 305-0044 Japan ma.nattapol@nims.go.jp.

Chemical science
|May 24, 2024
PubMed
概括

协调聚合物 (CP) 和金属有机框架 (MOF) 可以过渡到液态,提供超越其晶体形式的独特特性. 本综述探讨了这些金属有机液体及其尚未开发的潜力.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 化学 化学 化学

背景情况:

  • 协调聚合物 (CP) 和金属有机框架 (MOF) 传统上作为晶体固体进行研究.
  • 新兴研究揭示了CP和MOF中可逆的晶体到液体过渡.
  • 已经忽视了CP和MOF的流动状态,但对于新功能来说至关重要.

研究的目的:

  • 审查目前关于CP和MOF流动状态的研究.
  • 讨论控制这些转变的基本概念.
  • 探索金属有机液体的独特特性和应用.

主要方法:

  • 关于CP和MOF中的晶体-液体过渡的文献综述.
  • 分析不同的过渡类型.
  • 将概念扩展到相关的金属有机液体.

主要成果:

  • CP和MOF表现出各种各样的晶体到液体的过渡.
  • 液态具有在晶体形式中无法找到的独特特性.
  • 在离子液体和多孔液体等领域的潜在应用.

结论:

  • 了解和控制流动状态是释放新CP/MOF功能的关键.
  • 金属有机液体在材料科学中是一个有前途的前沿领域.
  • 未来的研究应该专注于探索和利用这些液体的特性.