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稳定六二酸盐阴极通过低含量的Cs离子为水性离子电池
Zhiqiu Pan1, Gang Ni1,2,3, Yi Li1
1School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, 23009, Anhui, P. R. China.
ChemSusChem
|May 24, 2024
概括
将酸 (Cs +) 添加到电解质中,可以显著提高可充电水性离子电池 (RAZIB) 中的六酸 (ZnHCF) 阴极材料的稳定性和循环性能. 这种稳定策略可以提高容量保留和电池寿命.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 可充电的水性离子电池 (RAZIB) 需要稳定的阴极材料来实现实际应用.
- 六酸 (ZnHCF) 作为阴极具有前景,但电化学稳定性差,容量衰减.
研究的目的:
- 为了提高RAZIB中ZnHCF的循环性能和电化学稳定性.
- 为了研究性金属电解质添加剂对ZnHCF行为的影响.
主要方法:
- 使用低度的性金属酸,特别是Cs+,作为电解质添加剂.
- 研究了ZnHCF在电池循环期间的间歇化学和结构变化.
- 在带有或没有Cs+添加剂的ZnHCF/Zn充满电池上进行了电化学循环测试.
主要成果:
- Cs+联合插入稳定了ZnHCF宿主结构,形成了一个保护性的CsZn[Fe(CN) 6相,减少了材料溶解.
- 添加Cs+抑制了ZnHCF转化为无活相,减轻了不可逆转的容量损失.
- 在300个周期以0.25 A/g加0.03 M Cs2SO4后,容量保留从7.0%提高到54.6%.
结论:
- 金属酸,特别是Cs+,是有效的电解质添加剂,可以增强RAZIB中的ZnHCF稳定性.
- 这项研究提供了对控制ZnHCF性能的电化学机制的见解,有助于未来的材料优化.
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