将已耗尽的离子交换树脂模拟物纳入水泥复合材料中
Yusif S El-Sayed1, Samir B Eskander2, Talat A Bayoumi2
1Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt.
概括
普通的波特兰水泥有效地固定了废弃的放射性离子交换树脂. 这项研究证实了水泥水泥的存在.
科学领域:
- 材料科学 材料科学 材料科学
- 核工程 核工程是指核工程.
- 环境科学 环境科学
背景情况:
- 废弃的放射性离子交换树脂 (IER) 对核工业构成了重大挑战.
- 固化/稳定 (S/S) 对于处理放射性废物至关重要.
- 普通波特兰水泥 (OPC) 是一种用于固定危险材料的常见矩阵.
研究的目的:
- 调查将模拟的IER纳入OPC矩阵中的情况.
- 描述最终废物形式 (FWF) 的特性.
- 评估水/水泥比率和树脂度对FWF特性的影响.
主要方法:
- 进行了实验室规模的实验.
- 机械完整性,热分析和质量损失在28天内进行了评估.
- 使用扫描电子显微镜 (SEM) 和X射线衍射 (X-RD) 的微结构分析.
- 在工艺过程中监测水泥水化热量.
主要成果:
- 该研究系统地分析了影响FWF属性的因素.
- 评估了机械和热性能,以及硬化过程中的质量损失.
- SEM和X-RD提供了关于固化废物形式的内部结构的见解.
- 在固定过程中记录了水分的热量.
结论:
- 普通波特兰水泥表现出可接受的特性,作为IER固定不动的惰性矩阵.
- 水泥为安全地固定未经处理的放射性离子交换树脂提供了优势.
- 开发的FWF具有适合放射性废物管理的性能.
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