全套生物衍生聚合物 (L-乳酸) 基复合材料,具有耐火性和烟雾抑制性能
Chen Wang1, Xiaolei Zhang1, Masrina Mohd Nadzir2
1Tianjin Key Laboratory of Hazardous Waste Safety Disposal and Recycling Technology, School of Environmental Science and Safety Engineering, Tianjin University of Technology, 391 Binshui Xidao, Xiqing District, Tianjin 300384, China.
International journal of biological macromolecules
|May 24, 2024
概括
环保的阻燃剂,改性酸盐 (C-CS) 和聚酸盐 (APP),明显改进的聚-乳酸 (PLA) 复合材料. 由此产生的材料提供了增强的耐火性,紫外线吸收性和抗菌性能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 消防安全工程 消防安全工程
背景情况:
- 聚L-乳酸 (PLA) 是一种生物衍生聚合物,由于易燃性,其应用有限.
- 开发环保,多功能阻燃PLA复合材料对于更广泛的材料利用至关重要.
研究的目的:
- 研究生物基基托 (C-CS) 和聚酸盐 (APP) 对PLA的协同阻燃作用.
- 评估C-CS/APP对基于PLA的复合材料的耐火性和其他性能的影响.
主要方法:
- 制备PLA复合材料,其中包含一个协同阻燃剂 (C-CS/APP).
- 使用有限氧指数 (LOI) 和圆热量计测试对消防性能进行评估.
- 评估额外的特性,包括紫外线吸收,抗菌作用,水性和结晶性.
主要成果:
- 该PLA/5%C-CS/5%APP复合材料获得了V-0的消防安全评级,LOI增加了37%.
- 观察到高峰热释放率 (26.5%) 和总烟雾产量 (68.3%) 的显著降低.
- 焦炭残留产量增加了46倍,证明了增强的焦炭形成能力和凝结相火焰阻燃性.
- 该复合材料还表现出改善的紫外线吸收,抗菌活性,水性和结晶性.
结论:
- C-CS/APP协同系统有效地为PLA复合材料提供了出色的耐火性.
- 增强的煤炭残留物作为物理屏障,抑制燃烧.
- 这些多功能PLA复合材料提供了一个有前途的环保替代品,具有更好的安全性和性能特性.
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