关于自发分散是金属融的微分层的原因
Olga A Chikova1, Vladimir S Tsepelev2, Kseniya Yu Shmakova2
1Departament of Physics, Ural Federal University, Yekaterinburg 620002, Russia.
Materials (Basel, Switzerland)
|May 25, 2024
概括
自发分散导致金属融中的微分层,导致原子或体颗粒大小. 这种现象使用Volmer进行了评估.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 金工业是金工业的一个方面.
背景情况:
- 金属融中的微分层与自发分散有关.
- 这个过程涉及到违反远程原子秩序 (LRO),导致分散的粒子.
- 微分离发生在液体和固体金属接触或两种液体金属混合时.
研究的目的:
- 评估各种金属融物中自发分散的可能性.
- 用Volmer的标准,Rehbinder的标准和扩散率标准来评估分散.
- 为了确定微分层形成的粒子大小.
主要方法:
- 使用三个不同的标准来评估自发分散:Volmer的标准,Rehbinder的标准和扩散率标准.
- 扩散速率标准是从速率过程理论中得出的.
- 分析不同金属化系统中的颗粒大小.
主要成果:
- 化Al-Sn呈现着环状颗粒 (4纳米);化Al-Si和化Al-Ge呈现出原子尺度颗粒 (0.1纳米).
- Cu-Ni固体溶液显示了2nm的分散颗粒.
- 末端欧体GaInSn的粒子为5.6nm,不混合的Cu-Fe化物显示为4.8nm的粒子.
- 在GaInSn,Al-Sn和Cu-Fe溶液中观察到长距离秩序违反和用体颗粒 (>20nm) 的微分层.
结论:
- 自发分散是金属融微分层的关键因素.
- 该研究量化了各种金属系统的粒子大小,从原子到合体尺度.
- 不同的相位图和融化成分会影响微分层和粒子形成的程度.
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