地质聚合反应对高基系统的柔性强度的影响
Binghuan Gao1,2, Yangyang Li1,2, Seongwan Jang1
1Department of 3D Printing Materials, Korea Institute of Materials Science (KIMS), Changwon 51508, Republic of Korea.
Materials (Basel, Switzerland)
|May 25, 2024
概括
控制/的比率和固化时间可以增强地质聚合反应. 这种优化改进了微观结构并增加了屈曲强度,这对于建筑和辐射屏蔽应用至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 无机化学 无机化学
- 纳米技术纳米技术
背景情况:
- 地质聚合物在建筑和辐射屏蔽中提供了多样化的应用,需要卓越的机械性能.
- 了解地质聚合反应及其对机械性能的影响仍然是一个挑战.
研究的目的:
- 研究Si/Al比率和固化时间对地质聚合物的影响.
- 为了将地质聚合物微观结构和化学结合与屈曲强度相关联.
主要方法:
- 扫描电子显微镜 (SEM) 用于微观结构分析.
- 福里埃转换红外光谱 (FTIR) 用于化学结合.
- 进行X射线衍射 (XRD) 和峰值解卷以量化反应程度.
- 柔性强度测试. 柔性强度测试. 柔性强度测试. 柔性强度测试. 柔性强度测试.
主要成果:
- 地质聚合物微结构从分层的高酸演变为3D sodalite 网络.
- 一个明显的FTIR峰值在973厘米-1表示酸水合物 (N-A-S-H) 链接,量化地质聚合.
- 在Si/Al比率为1.94和7天硬化时,达到55%的最大反应度.
- 屈曲强度与反应度有成比例的关系,在45%度时达到21.11 MPa.
结论:
- /比和固化时间有效控制地质聚合度.
- 优化地质聚合导致增强的机械强度.
- 通过控制反应开发高性能地质聚合物的洞察力.
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