填充弹性体:机械和物理驱动的建模和应用作为智能材料
Weikang Xian1, You-Shu Zhan1, Amitesh Maiti2
1Department of Mechanical Engineering, University of Wisconsin-Madison, Madison, WI 53706, USA.
Polymers
|May 25, 2024
概括
本综述探讨了填料颗粒微观结构和聚合物相互作用如何影响聚合物矩阵复合材料 (PMC) 的机械性能. 了解这些关系是设计先进弹性体和智能材料的关键.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 复合材料 复合材料 复合材料
背景情况:
- 弹性体为大变形形成网络;具有耐热性,而热塑性弹性体不需要固化.
- 填充物颗粒增强了弹性体的机械性能,但它们的空间分布显著影响了复合材料的行为.
- 对聚合物矩阵复合材料 (PMCs) 的基本理解在结构-属性关系方面仍然不完整.
研究的目的:
- 审查PMC机械性质和填充颗粒微观结构之间的关系.
- 检查填充剂-聚合物相互作用及其对复合材料行为的影响.
- 讨论智能聚合物矩阵复合材料 (PMC) 及其构成模型.
主要方法:
- 文献综述侧重于PMC中的微观结构与属性关系.
- 填充物颗粒分布效应的分析 (初级,二级,三级结构).
- 聚合物-粒子相互作用及其对聚合物矩阵接口的影响的审查.
主要成果:
- 软矩阵控制弹性;强化源于聚合物-粒子相互作用.
- 填充剂透超过一个值显著提高性能.
- 粘弹性与矩阵相关,而穆林斯和佩恩效应与微观结构细节相关.
结论:
- 微结构,填充剂-聚合物相互作用和接口决定PMC机械性能.
- 智能PMC (磁弹性,形状记忆,自我修复) 提供了先进的功能.
- 构成模型对于理解和设计这些先进的复合材料至关重要.
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