在消费食品包装中对化物和多化物质的非向分析
Kevin M Stroski1, Yelena Sapozhnikova2, Raegyn B Taylor2
1USDA, Agricultural Research Service, Eastern Regional Research Center, Wyndmoor, PA, USA; Baylor University, Waco, TX, USA.
Chemosphere
|May 26, 2024
概括
一种新的高分辨率质谱法 (HRMS) 方法在食品包装中发现了未知的和多基物质 (PFAS). 这项研究揭示了各种包装类型中广泛存在的PFAS污染,包括新型化合物.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
- 食品科学 食品科学 食品科学
背景情况:
- 和多基基物质 (PFAS) 在食品包装中被广泛使用.
- 有关PFAS从包装进入食品中的存在和迁移存在担忧.
- 对食品包装中PFAS的全谱,特别是未知化合物的知识有限.
研究的目的:
- 开发和验证一种非向的高分辨率质谱 (HRMS) 工作流程,用于识别食品包装中的未知PFAS.
- 调查各种食品包装材料中PFAS的流行程度和类型.
- 评估已识别的PFAS的迁移到食品模拟剂中的情况.
主要方法:
- 开发了一个非目标 HRMS 工作流程,包括负质缺陷,诊断故障结构和保留时间预测.
- 应用甲醇提取,控制的迁移与食品模拟剂,和总可氧化前体 (TOP) 测定食品包装样本.
- 利用HRMS进行PFAS特征的全面分析.
主要成果:
- 在所有测试的食品包装样本中检测到潜在的PFAS特征,无论材料或食品类型如何.
- 使用分析标准证实了五种化合物,包括6:2甲基酸二 (6:2二PAP) 和2H-二酸 (6:2FTUCA),使用分析标准.
- 在包装中发现了长链 perfluorocarboxylic 酸 (C17,C19-C24); 6:2 FTUCA 迁移到食品模拟剂中.
结论:
- 开发的非向HRMS工作流程有效地识别了食品包装中已知的和以前未知的PFAS.
- 消费者食品包装中普遍存在PFAS污染,这凸显了需要更广泛的分析方法.
- 这些发现强调了非向方法对于食品接触材料中PFAS综合风险评估的重要性.
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