在高温下煤灰的融化和流动行为基于SiO2-Al2O3-CaO/Na2O伪二次相位图
Ping Li1,2, Haoyong Kan2, Cai Chen2
1School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221116, China.
ACS omega
|May 27, 2024
概括
煤灰的组成显著影响了流动式气化器中的化渣流. 了解渣渣的理解 渣渣的理解
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 热力学是一种热力学.
背景情况:
- 引流气化器对不同类型的煤炭具有很高的适应性.
- 煤灰的组成是化渣高温流动特征的关键决定因素.
研究的目的:
- 为了研究在关键阶段区域 (野,梅石,二氧化,聚石) 中的渣的高温融流特征.
- 为了阐明煤灰成分对渣渣流动性和融化行为的影响.
主要方法:
- 使用SiO2-Al2O3-CaO/Na2O三元相图来指导实验设计.
- 进行了实验和热力学软件计算,以分析废渣的特性.
- 采用红外光谱学来识别融渣中的主导离子集群.
主要成果:
- 融化过程在研究的各个阶段区域 (野,石,二氧化,石) 中各不相同.
- 菲尔斯巴特地区的污泥显示Si2O5^2-离子集群占主导地位.
- 二氧化区域的渣呈现出更高比例的简单酸盐离子集群,与田区域相比,导致流动性得到改善.
结论:
- 煤灰的组成直接影响了渣的化和流动行为.
- 了解渣离子集群的形成是预测和控制流动性的关键.
- 结果提供了关于煤灰融机制的见解,并指导工业煤炭混合战略,以优化气化.
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