局部化高度硫电解质,具有高压稳定性和阻燃性,用于Ni-丰富的金属电池
Bo-Han Zhang1,2, Pei-Pei Chen1,2, Yun-Lei Hou1,2
1State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, 100029, P. R. China.
Small (Weinheim an der Bergstrasse, Germany)
|May 28, 2024
概括
这项研究介绍了一种基于硫的局部高度电解质 (LHCE) 用于高压电池的新型电解质. 先进的电解质在富含的系统中提高了循环稳定性和热安全性,即使在苛刻的条件下也是如此.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 局部高度电解质 (LHCE) 对于先进的高压电池系统至关重要.
- 基于硫的LHCE为实现高能量密度和提高安全提供了有前途的途径.
- 研究特定的盐和稀释剂组合是优化LHCE性能的关键.
研究的目的:
- 研究二三甲硫胺和二硫胺 (LiFSI) 在硫基LHCE中的应用.
- 分析稀释剂添加对离子对形成和溶解结构的影响.
- 为了评估设计的电解质在富含Ni的高压电池系统中的性能.
主要方法:
- 使用硫和TTE与LiFSI添加剂的硫基LHCE的配方.
- 在4.5V时对富含的阴极进行电化学循环测试.
- 分析电解质组成和接口形成.
- 热稳定性测试和现场凝研究.
主要成果:
- 添加稀释剂增加了离子对和离子聚合物,同时保持了自由溶剂分子.
- LiFSI与TTE协同分解,有助于稳定的电极接口.
- 富含的系统在4.5V时表现出稳定的循环,在高质量负载和精益电解质条件下,在50个循环后保持91.5%的容量.
- 与商业电解质相比,基于硫的电解质表现出优越的热稳定性.
结论:
- 开发的硫基LHCE与LiFSI添加剂可使富含Ni的电池在稳定的高压运行.
- 电解质显示出优异的热稳定性和凝电解质发展的潜力.
- 这项工作为为下一代电池设计高性能,安全和稳定的电解质提供了基础.
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