相关实验视频
Updated: Jun 25, 2025

06:19
Fractionation of Lignocellulosic Biomass using the OrganoCat Process
Published on: June 5, 2021
3.9K
通过一步酸性单相氧乙醇分离法对纤维素的价值化
Yiqi Zhang1,2, Yunxuan Wang3, Wuhuan Li1,2
1Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, CAS Key Laboratory of Renewable Energy, Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou, 510640, PR China.
ChemSusChem
|May 29, 2024
概括
本研究介绍了一种有效的生物质分成方法,使用酸化单相氧乙醇 (EPH). 这一过程允许在温和条件下对素,西兰和纤维素成分进行价值化.
科学领域:
- 生物质的价值化 生物质的价值化
- 绿色化学 绿色化学
- 生物精炼是生物精炼的一种方式.
背景情况:
- 红纤维素生物质是一种可持续的资源,但高效分离具有挑战性.
- 目前的方法通常需要严苛的条件,限制组件的价值化.
- 开发温和有效的预处理策略对于生物提炼至关重要.
研究的目的:
- 为了实现有效的细分基纤维素生物质.
- 在温和的条件下利用所有主要的生物质成分 (木质素,西兰,纤维素).
- 评估一种新型的加酸单相氧乙醇 (EPH) 预处理方法.
主要方法:
- 生物质预处理使用化单相氧乙醇 (EPH) 在110°C下60分钟.
- 隔离和表征素,西兰 (作为EPH-xyloside) 和富含碳水化合物的固体残留物.
- 脱乙后的碳水化合物残留物的酶性水解.
- 在像松木这样的反抗生物质上测试EPH.
主要成果:
- 从树生物质中去除92.6%的红素和80%的西兰.
- 在轻度处理后,碳水化合物残留的高酶消化率 (92.3%).
- 恢复高纯度,未缩的EPH改性红素 (EPHL).
- 氧化转化为EPH-氧化,一种潜在的生物医学前体.
- 在相同的温和条件下,松木的成功脱 (>70%).
结论:
- 酸性单相EPH预处理可以有效和温和地分离纤维素生物质.
- 这种方法可以将所有主要的生物质成分利用成有价值的产品.
- EPH工艺显示出广泛的适用性,包括对强硬的木质生物质,突出其可持续生物提炼的潜力.
相关概念视频
Carboxylic Acids to Esters: Acid-Catalyzed (Fischer) Esterification Overview
17.9K
The Fischer esterification reaction was developed by the German chemist Emil Fischer in 1895. It is a condensation reaction between carboxylic acids and alcohols in an acidic medium to give esters and water.
17.9K
Esters to Carboxylic Acids: Acid-Catalyzed Hydrolysis
2.8K
Hydrolysis of esters under acidic conditions proceeds through a nucleophilic acyl substitution. In the presence of excess water, the reaction proceeds in a reversible manner, forming carboxylic acids and alcohols.
During hydrolysis, the ester is first activated towards nucleophilic attack through the protonation of the carboxyl oxygen atom by the acid catalyst. The protonation makes the ester carbonyl carbon more electrophilic. In the next step, water acts as a nucleophile and adds to the...
During hydrolysis, the ester is first activated towards nucleophilic attack through the protonation of the carboxyl oxygen atom by the acid catalyst. The protonation makes the ester carbonyl carbon more electrophilic. In the next step, water acts as a nucleophile and adds to the...
2.8K
Acid-Catalyzed Dehydration of Alcohols to Alkenes
19.5K
In a dehydration reaction, a hydroxyl group in an alcohol is eliminated along with the hydrogen from an adjacent carbon. Here, the products are an alkene and a molecule of water. Dehydration of alcohols is generally achieved by heating in the presence of an acid catalyst. While the dehydration of primary alcohols requires high temperatures and acid concentrations, secondary and tertiary alcohols can lose a water molecule under relatively mild conditions.
19.5K

