对无水和水性REE酸盐,氧化物和氧化物的拉曼光谱研究
Nicole C Hurtig1, Alexander P Gysi1,2, Sarah E Smith-Schmitz2
1Dept. of Earth and Environmental Sciences, New Mexico Institute of Mining and Technology, 801 Leroy Place, 87801 Socorro, USA. nicole.hurtig@nmt.edu.
Dalton transactions (Cambridge, England : 2003)
|May 29, 2024
概括
本研究汇编了稀土元素 (REE) 氧化物,氧化物和酸盐的参考拉曼光谱. 这些发现揭示了与雷曼光谱相关联的REE离子半径的系统趋势,有助于矿物识别.
科学领域:
- 矿物学和光谱学 矿物学和光谱学
- 材料科学为绿色能源提供绿色能源
背景情况:
- 稀土元素 (REE) 对绿色能源技术至关重要.
- REE的离子半径随着原子数的减少而减少,导致兰坦化物收缩并影响矿物质的性质.
研究的目的:
- 编制各种REE化合物的参考拉曼光谱.
- 确定REE-O拉曼波段的系统趋势.
- 为确定REE阶段提供一个框架.
主要方法:
- 对分析工作和理论计算的文献综述.
- 对REE氧化物,氧化物,氧化物,氧化物,莫纳和拉布多的拉曼光谱分析.
- 使用多个激光波长的光发光谱学.
主要成果:
- 随着离子半径的减少,REE-O拉曼波段波数的系统增加.
- 在同结构REE矿物群中观察到的线性趋势.
- 使用拉曼和光发光学成功识别了REE相.
结论:
- 拉曼光谱为估计矿物中的REE-O模式提供了一个工具.
- 光发光为REE相识别提供了一个补充方法.
- 这项工作为REE矿物质表征奠定了基础.
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