键对冷保护剂溶液状态图的影响
相关实验视频
Updated: Jun 25, 2025

09:50
Measuring the Densities of Aqueous Glasses at Cryogenic Temperatures
Published on: June 28, 2017
8.7K
1Institute for Problems of Cryobiology and Cryomedicine of the National Academy of Sciences of Ukraine, Kharkiv, Ukraine. cryoo@ukr.net.
Cryo letters
|May 29, 2024
概括
在冷却过程中,像甘和DMSO这样的冷保护剂溶液形成独特的纳米结构,而不是经典的eutectic. 这些集群相显著改变了它们的状态图,影响了冷保护策略.
科学领域:
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
- 生物物理学的生物物理.
背景情况:
- 研究了冷保护剂溶液状态图的转化.
- 专注于微弱的分子内相互作用的影响.
研究的目的:
- 分析水性甘油和DMSO溶液的相位.
- 为了确定键影响结晶-化动态的温度.
- 为这些冷保护剂溶液绘制准确的状态图.
主要方法:
- 采用体积扫描张伸度计.
- 研究的溶液在+25°C至-150°C的温度范围内.
- 确定影响键对结晶的影响的临界温度.
主要成果:
- 建立了绘制弱分子间相互作用的二进制溶液状态图的原则.
- 观察冰的微晶和冷保护剂集群的形成.
- 开发了甘油和DMSO溶液的状态图,包括一个独特的集群阶段区域.
结论:
- 分析了冷却后在冷却剂溶液中形成的纳米结构.
- 证明这些结构从根本上不同于经典的固体阶段eutectics.
- 突出了集群形成在冷保护剂行为中的意义.
相关概念视频
Entropy and Solvation
7.0K
The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for determining a solvent for a given compound is that like dissolves like. A good solvent has molecular characteristics similar to those of the compound to be dissolved. For example, polar solutions dissolve polar solutes, and apolar solvents dissolve apolar solutes. A polar solvent is a solvent that has a high dielectric constant (ϵ...
7.0K
Hydrogen Bonds
8.4K
A hydrogen bond is formed when a weakly positive hydrogen atom already bonded to one electronegative atom (for example, the oxygen in the water molecule) is attracted to another electronegative atom from another polar molecule, such as water (H2O), hydrogen fluoride (HF), or ammonia (NH3). The huge electronegativity difference between the H atom (2.1) and the atom to which it is bonded (4.0 for an F atom, 3.5 for an O atom, or 3.0 for an N atom), combined with the very small size of an H atom...
8.4K
Comparing Intermolecular Forces: Melting Point, Boiling Point, and Miscibility
44.3K
Intermolecular forces are attractive forces that exist between molecules. They dictate several bulk properties, such as melting points, boiling points, and solubilities (miscibilities) of substances. Molar mass, molecular shape, and polarity affect the strength of different intermolecular forces, which influence the magnitude of physical properties across a family of molecules.
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...
44.3K
Aqueous Solutions and Heats of Hydration
14.7K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
14.7K
Intermolecular Forces in Solutions
33.2K
The formation of a solution is an example of a spontaneous process, a process that occurs under specified conditions without energy from some external source.
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
33.2K
Phase Diagrams
40.6K
A phase diagram combines plots of pressure versus temperature for the liquid-gas, solid-liquid, and solid-gas phase-transition equilibria of a substance. These diagrams indicate the physical states that exist under specific conditions of pressure and temperature and also provide the pressure dependence of the phase-transition temperatures (melting points, sublimation points, boiling points). Regions or areas labeled solid, liquid, and gas represent single phases, while lines or curves represent...
40.6K

