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探索缺陷工程金属有机框架与1,2,4-Triazolyl异甲酸盐和酸盐连接器

Sibo Chetry1, Muhammad Fernadi Lukman2, Volodymyr Bon3

  • 1Faculty of Chemistry and Mineralogy, Universität Leipzig, Johannisallee 29, Leipzig 04103, Germany.

Inorganic chemistry
|May 29, 2024
PubMed
概括

缺陷工程金属有机框架 (DEMOF) 使用混合链接器方法进行了合成. 这种方法成功地在框架中创建了协调不和位点 (CUS),增强了气体吸附特性.

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Imperfections in Crystal Structure: Non-Stoichiometric Defects01:29

Imperfections in Crystal Structure: Non-Stoichiometric Defects

Non-stoichiometric defects refer to a type of defect in the crystal structure of a compound where the ratio of its constituent elements deviates from the ideal stoichiometric ratio. There are two main types of non-stoichiometric defects: metal excess defects and metal deficiency defects.Metal excess defects occur when there is a slight surplus of metal ions than what is required by the stoichiometric ratio of the compound. For example, heating a sodium chloride crystal in sodium vapor results...
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