在石墨烯-MoS2的电荷转移垂直异构结构通过堆叠顺序调整和基板引入的电场
Yuqing Zou1, Zeyu Zhang2,3, Chunwei Wang2,4
1Department of Physics, Shanghai University, Shanghai 200444, China.
ACS applied materials & interfaces
|May 30, 2024
概括
我们研究了石墨烯-二硫化物异构结构,揭示了基板电场如何控制电荷转移. 这项工作有助于开发先进的光电子设备.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 纳米技术纳米技术
背景情况:
- 石墨烯 (Gr) 和过渡金属二甲基化物 (TMD) 的垂直范德瓦尔斯异构结构是二维光电子学的关键.
- 了解Gr/TMD中的接口电荷动态至关重要,但仍然不完整.
研究的目的:
- 在Gr-MoS2异构结构 (Gr/MoS2和MoS2/Gr) 中研究载体动力学.
- 阐明基板电场对界面电荷转移 (CT) 的影响.
主要方法:
- 超快速光谱学:时间分辨率的太赫兹 (THz) 光谱学,THz发射光谱学和短暂吸收光谱学.
- 研究了具有不同光刺激能量的Gr-MoS2异构结构.
主要成果:
- 基板电场显著调节界面CT效率.
- Gr/MoS2显示了从石墨烯到MoS2的热电子注入低于A-激发能量的情况.
- 由于基板电场,MoS2/Gr 展示了由于基板电场而阻塞的CT.
- 在A-激子以上的光刺激导致从MoS2到石墨烯的孔转移,产生相反的光电流.
- 界面刺激子重组是~18 ps;缺陷辅助重组是~ns.
结论:
- 在Gr-TMD中,界面CT受到基底效应和堆叠顺序的强烈影响.
- 缺陷工程可以调整重组动态.
- 这些发现有助于设计下一代光电子设备.
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