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Updated: Jun 25, 2025

Supercritical Nitrogen Processing for the Purification of Reactive Porous Materials
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Supercritical Nitrogen Processing for the Purification of Reactive Porous Materials

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混合金属化物-化物固体解决方案,用于潜在的储能应用.

Thi Thu Le1, Simone Bordignon2, Michele R Chierotti2

  • 1Institute of Hydrogen Technology, Helmholtz-Zentrum hereon GmbH, Max-Planck-Straße 1, Geesthacht D-21502, Germany.

Inorganic chemistry
|May 30, 2024
PubMed
概括

研究人员通过组合1组元素,创造了新的混合金属化物-化物固体溶液. 这些M-N-H材料显示出改善储存和离子导电性应用的潜力.

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Amides to Amines: LiAlH4 Reduction01:20

Amides to Amines: LiAlH4 Reduction

Amide reduction with strong reducing agents like lithium aluminum hydride proceeds through a nucleophilic acyl substitution to form amines. Primary, secondary, and tertiary amides yield primary, secondary, and tertiary amines, respectively.
Amide reduction requires two equivalents of the reducing agent, acting as a source of hydride ions. As shown in the figure, the reaction is initiated with a nucleophilic attack by the hydride ion at the carbonyl carbon to form a tetrahedral intermediate.
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