在环境条件下,挥发性有机化合物在袋取样系统中的短期储存能力
Seung-Ho Ha1, Younes Ahmadi1, Hye-Jin Shin1
1Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul, 04763, Republic of Korea.
Environmental research
|May 30, 2024
概括
对挥发性有机化合物 (VOC) 的袋式采样可以引入偏差. 这项研究在24小时内评估了聚乙烯袋中的27种挥发性有机化合物,发现了显著的变化和损失,特别是对于化物和分支化合物.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
- 空气质量监测 空气质量监测
背景情况:
- 袋式采样是量化挥发性有机化合物 (VOC) 的常用方法.
- 然而,VOCs在采样袋中可能不稳定,导致实验偏差,特别是在短储存时间 (<24小时) 中.
- 了解不同VOC的时间稳定性对于准确的空气质量评估至关重要.
研究的目的:
- 为了评估27个挥发性有机化合物 (VOC) 在24小时内存储在聚乙烯 (PEA) 袋中的时间稳定性.
- 确定影响VOC降解的因素,并评估袋式采样对VOC量化的可靠性.
- 提供准确测量空气样本中的VOC的指导方针.
主要方法:
- 使用PEA袋评估了27种VOC的时间稳定性,涉及五种类型 (化物,芳香碳水化合物,碳酸,,杂类).
- 在五个时间间隔测量VOC度:0.17,1,2,6和24小时.
- 分析了使用相对标准误差 (RSEt) 的可复制性和使用相对回收 (RR) 的回收,考虑气/液 (G/L) 比率.
主要成果:
- 非极性芳香碳化合物 (BTXS) 的可重复性最高 (平均RSE<1.55%).
- 在气态标准制备过程中发生了显著的VOC损失,其分子量较低,分支类化物具有高的G/L比率.
- 总体VOC回收在24小时内呈指数级下降;BTXS保持高回收率 (>94.3%),而英多尔和斯卡托尔显示显著降解 (RR <24.6%).
结论:
- 在PEA袋中,VOC的储存能力受分子量,分支和储存时间的影响.
- 袋子采样引入了由于VOC不稳定的实验偏差,需要仔细考虑储存时间和化合物特性.
- 准确量化VOCs需要考虑这些稳定性问题,BTXS是测试中最稳定的类别.
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