,硫协同协调的铁单原子催化剂具有优化的电子结构,用于高效的氧气减少Zn-空气电池和燃料电池
Hao Xu1, Ruopeng Li2, Huan Liu1
1College of Chemical Engineering, Inner Mongolia University of Technology, 010051 Hohhot, China; Inner Mongolia Key Laboratory of Industrial Catalysis, 010051 Hohhot, China.
Journal of colloid and interface science
|May 31, 2024
概括
在铁--碳 (Fe-N-C) 催化剂中引入硫,可优化单原子铁位点,减少氧气. 这种工程化Fe-N-C催化剂在和酸性条件下表现出卓越的活性和稳定性,增强了Zn-空气电池和燃料电池.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 催化剂是一种催化剂.
背景情况:
- 原子分散的铁--碳 (Fe-N-C) 材料是氧降解反应的有希望的催化剂.
- 在调整单原子铁位点的电子结构以改善催化动力学和活性方面仍然存在挑战.
研究的目的:
- 通过加入硫来设计Fe-N-C催化剂中单原子铁位点的协调环境.
- 研究硫协调对Fe-N-C材料电子结构和催化性能的影响.
主要方法:
- 一个定制的Fe-N-C催化剂 (FeSA/NSC) 的合成,具有N,S协调的Fe原子位点 (Fe-N3S).
- 利用结构特征和理论计算来分析催化剂的特性.
- 在性和酸性电解质中评估了催化活性和稳定性.
主要成果:
- 加入硫优化了Fe原子的电荷分布,减弱了OH*吸附,促进了脱附.
- 经S修改的FeSA/NSC催化剂实现了高半波电位 (0.915V在性电解质中,0.797V在酸性电解质中),具有良好的稳定性.
- 在气电池和燃料电池中表现出色的性能,显示出高峰功率密度.
结论:
- 通过加入硫的协调环境工程是一种有效的策略,可以增强单原子铁催化剂的内在活性.
- FeSA/NSC催化剂显示出在能量转换设备 (如气电池和燃料电池) 中应用的巨大潜力.
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