聚合物玻璃在变形过程中的结构松时间
Pradip K Bera1, Grigori A Medvedev2, James M Caruthers2
1University of Wisconsin-Madison, Madison, Wisconsin 53706, USA.
Physical review letters
|June 3, 2024
概括
在变形的聚合物玻璃中测量了结构放松时间,使用应变速率切换实验. 分段相关时间直接量化了这种放松,与聚合物变形模型保持一致.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物物理 聚合物物理
- 类风病学 类风病学 类风病学
背景情况:
- 了解聚合物玻璃在变形时的行为对于材料设计至关重要.
- 结构松决定了聚合物的机械反应.
- 以前的模型经常简化了聚合物玻璃在流动过程中的复杂动态.
研究的目的:
- 通过实验确定聚合物玻璃在塑性变形过程中的结构松时间.
- 在变形过程中将细分运动与宏观应力反应相关联.
- 为了验证现有的聚合物变形模型.
主要方法:
- 在稳态塑料流量状态下,对交联聚甲酸 (PMMA) 玻璃进行了延展率切换实验.
- 使用光学探头重定位技术量化细分运动.
- 分析了非单调的应激反应和分段相关时间的单调演变.
主要成果:
- 在应变速率切换后观察到非单调的应激反应,与之前的研究一致.
- 证明了细分相关时间单调地演变为新的稳定状态.
- 发现结构放松时间大约等于细分相关时间.
- 陈-瑞士模型有质地预测了观察到的动态.
结论:
- 分段相关时间提供了在聚合物玻璃变形过程中结构放松时间的明确衡量.
- 实验结果支持聚合物变形建模中的材料时间假设.
- 将线性响应模型与依赖时间的细分相关时间结合起来,可以准确地描述聚合物玻璃的行为.
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