在室温下具有低磁场磁电的分子铁电
Zhao-Bo Hu1,2, Xinyu Yang3, Jinlei Zhang4
1State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.
Nature communications
|June 3, 2024
概括
研究人员开发了一种单相磁电材料,[TMCM][FeCl4],表现出室温磁电. 低磁场诱导磁阻,改变铁电极化,并使新的电子应用成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 化学 化学 化学
背景情况:
- 磁电材料为先进的电子产品提供了结合的磁性和电性.
- 由于竞争的铁电和磁性,实现理想的磁电电力是具有挑战性的.
- 寻求单相材料,以简化设备制造和提高性能.
研究的目的:
- 为了引入一种新的单相磁电材料,[TMCM][FeCl4].
- 为了证明在室温下低磁场磁电电.
- 探索磁力约束在实现磁电合中的作用.
主要方法:
- 合成单相偏磁铁电分子 [TMCM][FeCl4].
- 应用低磁场 (≤1kOe) 来诱导磁阻.
- 测量磁电张力元件和极化变化.
- 密度函数理论 (DFT) 计算用于模拟磁强化效应.
主要成果:
- 该材料在室温下表现出磁电性,对低磁场有反应.
- 在2kOe内平面磁场下,在a轴上观察到磁阻力,其变形为~10^-4在2kOe平面磁场下.
- 一个显著的磁电张力元件 (α31 ≈ 89 mV Oe−1 cm−1) 被诱导.
- 在40kOe磁场下,磁电合达到~12%.
结论:
- 介绍了一种新的设计策略,用于使用磁力约束的室温磁电.
- [TMCM][FeCl4] 作为开发磁电器件的有希望的平台.
- 这些发现为磁控电子元件和自旋电子应用铺平了道路.
相关概念视频
Ferromagnetism
2.4K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
2.4K
Paramagnetism
2.5K
Paramagnets are materials with unpaired electrons that possess a finite magnetic moment. In the absence of a magnetic field, these moments are randomly oriented, and thus the net moment is zero. Under an external field, a torque acting on the moments tends to align them along the field's direction. However, the random thermal motion of electrons produces a torque opposite to the external field and tries to disorient the moments. These two competing effects align only a few moments along the...
2.5K
Diamagnetism
2.4K
Materials consisting of paired electrons have zero net magnetic moments. However, when these materials are placed under an external magnetic field, the moments opposite to the field are induced. Such materials are called diamagnets. Diamagnetism is the response of the diamagnets when placed in an external magnetic field.
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
2.4K
Magnetostatic Boundary Conditions
909
An electric field suffers a discontinuity at a surface charge. Similarly, a magnetic field is discontinuous at a surface current. The perpendicular component of a magnetic field is continuous across the interface of two magnetic mediums. In contrast, its parallel component, perpendicular to the current, is discontinuous by the amount equal to the product of the vacuum permeability and the surface current. Like the scalar potential in electrostatics, the vector potential is also continuous...
909
Magnetic Susceptibility and Permeability
1.1K
In linear magnetic materials, like paramagnets and diamagnets, magnetization is proportional to the magnetic field intensity. The constant of proportionality, a dimensionless number, is called magnetic susceptibility. The value of the susceptibility depends on the type of material.
When diamagnetic materials are placed under an external magnetic field, the moments opposite to the field are induced. Hence, the susceptibility for diamagnets has a minimal negative value of 10-5–10-6. Since...
When diamagnetic materials are placed under an external magnetic field, the moments opposite to the field are induced. Hence, the susceptibility for diamagnets has a minimal negative value of 10-5–10-6. Since...
1.1K
Types Of Superconductors
972
A superconductor is a substance that offers zero resistance to the electric current when it drops below a critical temperature. Zero resistance is not the only interesting phenomenon as materials reach their transition temperatures. A second effect is the exclusion of magnetic fields. This is known as the Meissner effect. A light, permanent magnet placed over a superconducting sample will levitate in a stable position above the superconductor. High-speed trains that levitate on strong...
972


