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Updated: Jun 24, 2025

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Low-energy Cathodoluminescence for OxyNitride Phosphors
Published on: November 15, 2016
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在稀土基双岩石中,来自高分辨率激发状态结构的温度依赖光发光
Haowen Hou1, Shuai Zhang1, Haiyan Wang1
1State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures, School of Physical Science and Technology, Third Generation Semiconductor Industry Research Institute, Guangxi University, Nanning 530004, China.
ACS applied materials & interfaces
|June 4, 2024
概括
无化物双矿,添加了和,实现了高效的白光发射. 这些材料表现出温度依赖的双重排放,显示出固态照明和光学温度计的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 摄影化学的使用.
背景情况:
- 无化物双矿 (DPs) 正因其光学特性和可调的组成而引起人们的注意.
- 目前对DP的研究往往侧重于室温特性和单个排放频段.
研究的目的:
- 为了合成Cs2NaYCl6:Sb3+,Dy3+双矿.
- 为了实现白光发射,并研究它们的光学特性,包括温度依赖的发光.
主要方法:
- 溶解热合成方法.
- 光发光 (PL) 光谱学. 光发光 (PL) 光谱学.
- 光学表征和理论模拟计算.
主要成果:
- 合成的Cs2NaYCl6:Sb3+,Dy3+DPs具有70.7%的高PL量子产量.
- 观察到自陷激子 (STEs) 和Dy3+离子的温度依赖的双排放.
- 已证明Dy3+排放强度比的强烈温度依赖 (在360K时高达1.79%K-1).
结论:
- 证实了从STEs到Dy3+离子的能量转移.
- 合成的DP显示了固态照明,光学温度测量,夜视和辐射检测的潜力.
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