通过离子相互作用调制设计高安全性和长寿命的离子电解质
Hui Chen1, Kean Chen1, Jingyu Yang1
1College of Chemistry and Molecular Sciences, Hubei Key Laboratory of Electrochemical Power Sources, Wuhan University, Wuhan 430072, China.
Journal of the American Chemical Society
|June 4, 2024
概括
开发更安全的离子电池至关重要. 这项研究引入了一种新型低度酸盐电解质,提高了硬碳阳极SIB的安全性和性能.
科学领域:
- 电化学
- 材料科学
- 能量储存
背景情况:
- 可燃电解质对离子电池 (SIB) 构成重大安全风险.
- 现有的非易燃的电解质通常需要高度,这限制了与碳阳极的兼容性.
- 需要安全的高性能电解质,与SIB中的先进电极材料兼容.
研究的目的:
- 设计和开发低度,不易燃的酸盐电解质,以提高SIB的安全性和性能.
- 通过阴离子相互作用调制来研究电解质稳定机制.
- 用硬碳阳极和NFPP阴极证明开发的电解质的电化学兼容性和长期稳定性.
主要方法:
- 使用Tris ((2,2,2-trifluoroethyl) 酸盐 (TFEP) 作为辅溶剂的阳离子相互作用调节策略.
- 用光谱分析和理论计算来阐明电解质结构和稳定机制.
- 制造和测试Ah级硬碳 (HC) /Na4Fe2.91PO4) 2P2O7 (NFPP) 囊细胞
主要成果:
- 在低度 (1.22M) 酸盐电解质中实现了稳定的离子诱导离子溶剂协调结构 (AI-ISC).
- 开发的电解质与HC阳极和NFPP阴极均表现出良好的兼容性.
- HC//NFPP袋式电池具有高平均库伦比效率 (>99.9%),优异的容量保留率 (在2000个循环后为84.5%),广泛的操作温度范围 (-20至60°C),并通过了安全测试.
结论:
- 离子相互作用调制策略有效地稳定了SIBs的低度酸盐电解质.
- 开发的电解质为高安全性,长寿命的离子电池提供了有前途的解决方案.
- 这项研究为设计下一代储能系统的先进电解质提供了宝贵的见解.
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