液滴在滑聚合物刷上移动的动力学
Rodrique G M Badr1, Lukas Hauer2, Doris Vollmer2
1Institut für Physik, Johannes Gutenberg-Universität Mainz, Staudingerweg 7-9, D-55099 Mainz, Germany.
Langmuir : the ACS journal of surfaces and colloids
|June 4, 2024
概括
这项研究使用模拟来揭示水滴如何在聚合物涂层表面上移动. 滴滴滚动而不是滑动,滑剂对摩擦的影响最小,尽管影响表面结构.
科学领域:
- 软物质物理学 软物质物理学
- 表面科学是一门学科.
- 计算化学计算化学
背景情况:
- 了解聚合物表面的滴滴动态对于自洁材料和微流体等应用至关重要.
- 现有的研究描述了静态和动态特性,但缺乏对滴滴运动的微观洞察力.
- 由于实验的局限性,未交叉连接的聚合物链对滴滴行为的影响仍然不太清楚.
研究的目的:
- 为了研究液滴在滑聚合物刷基板上移动的微观动力学,在外力下.
- 探索滴滴速度与施加力之间的关系,以及滑剂如何影响这种相互作用.
- 阐明滴滴的滚动与滑动行为以及滑剂在摩擦中的作用.
主要方法:
- 使用多体消散粒子动力学 (MDPD) 方法进行粗粒度模拟.
- 在使用化学相同的PDMS滑剂的聚二甲西洛 (PDMS) 刷上建模水滴系统.
- 分析滴滴延长,接触角度变化和内部流量形状.
主要成果:
- 模拟重现了实验观察到的力和速度之间的线下功率定律 (F v^α,α < 1),尽管有不同的指数.
- 随着速度的增加,观察到滴滴的延长和缩小的接触角度;前进的接触角度保持不变.
- 分析显示,滴滴在基板上滚动时滑动不大,加上滑剂对摩擦影响最小,但改变了湿结构.
结论:
- 滑聚合物刷上的滴滴运动的特点是滚动,而不是滑动,表面的滑动最小.
- 滑剂的数量虽然影响了表面形态,但对有效的摩擦力的影响却惊人地有限.
- 模拟结果提供了对液滴动态的微观见解,补充了实验发现,并突出了滑剂和表面特性之间的复杂相互作用.
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