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具有逐步变形能力的光响应液晶聚合物的设计,合成和性能

Qin Gui¹, Zui Liu¹, Xiangling Sun¹

¹Key Laboratory of Polymeric Materials and Application Technology of Hunan Province, Key Laboratory of Advanced Organic Functional Materials of Colleges and Universities of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan, Hunan Province, 411105, China.

Macromolecular rapid communications

|June 5, 2024

概括

新的光敏液晶聚合物 (LCP) 提供连续的,逐步的变形控制. 这些先进的LCP利用烯和烯单体在灵活的机器人等应用中进行精确的,光感应的形状变化.

科学领域:

材料科学材料科学材料科学
聚合物化学聚合物化学
光电学是指光电子产品.

背景情况:

光响应液晶聚合物 (LCP) 对于灵活的机器人和人工肌肉等先进应用至关重要.
当前的LCP面临着实现连续和可控制的逐步变形的挑战.
开发具有可调节的照片诱导反应的LCP是一个活跃的研究领域.

研究的目的:

合成能够进行连续和可控制的逐步变形的新型光响应LCP.
调查烯和亚博烯含量对LCP变形的影响.
探索已开发的LCPs的多阶段光感应变形特性.

主要方法:

合成LCPs,其中包括对可见光敏感的烯和对紫外线光敏感的阿佐烯单体.
在LCP制备中使用多重键交叉连接剂.
在不同波长的光 (470nm蓝光和365nm紫外光) 下对光诱导变形的全面描述.

主要成果:

在LCP中,基于单体成分和光源的调节变形角度.
在470nm蓝光下,变形随着乙烯含量增加 (40°至0°) 而减少.
在365nm紫外线下,变形随着亚博含量 (0°至89.4°) 的增加而增加.
观察到持续的变形过程,通过切换光源,可以在变形阶段之间无过渡.

结论:

该研究成功地准备了光响应的LCP,具有可控制的逐步变形能力.
开发的LCP对不同波长的光有着不同的,可调节的反应.
这些发现为先进的LCP应用铺平了道路,在需要精确,光控制的执行的领域.

关键词:

亚博取款方式亚博取款方式亚博取款方式酸是一种酸.具有光响应性的液晶聚合物.逐步变形能力逐步变形能力

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