在极流体-螺旋电磁相中自发的奇拉对称性破裂
Jakub Karcz1, Jakub Herman1, Natan Rychłowicz1
1Faculty of Advanced Technology and Chemistry, Military University of Technology, Warsaw, Poland.
概括
研究人员观察到铁电阴性液晶相中的自发性性结构和极性秩序. 这种新的铁电阻相具有可以通过温度或电场调节的光反射特性.
科学领域:
- 材料科学
- 凝聚物质物理学
- 软物质物理学
背景情况:
- 在流体中,自发的镜像对称性破裂和极性秩序是罕见的.
- 这些现象在阴性液晶中已经分别观察到,但不是同时观察到的.
- 性分子通常不会形成性结构.
研究的目的:
- 在流体中同时观察自发性和极性秩序.
- 为了研究一种新型的螺旋体结构,
- 探索这种奇拉性铁电阻相的特性和潜在机制.
主要方法:
- 使用无体构建块来形成超分子结构.
- 研究了铁电阴性液晶相.
- 描述了螺旋结构及其光学特性.
主要成果:
- 在铁电阴性阶段内自组合成螺旋结构的阿基拉分子.
- 由此产生的阶段表现出自发的极性顺序和性.
- 发现螺旋结构的斜率处于可见光谱中,使选择性反射成为可能.
- 选择性反射可以通过温度或弱电场控制.
结论:
- 在铁电阴性液晶阶段,阿基拉分子可以同时形成极性和性结构.
- 这种性铁电阻相具有可调节的光学特性.
- 诱导非对线双极方向的电相互作用是这种现象的关键.
相关概念视频
Chirality
23.9K
Chirality is a term that describes the lack of mirror symmetry in an object. In other words, chiral objects cannot be superposed on their mirror images. For example, our feet are chiral, as the mirror image of the left foot, the right foot, cannot be superposed on the left foot.
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...
23.9K
Chirality in Nature
13.3K
Chirality is the most intriguing yet essential facet of nature, governing life’s biochemical processes and precision. It can be observed from a snail shell pattern in a macroscopic world to an amino acid, the minutest building block of life. Most of the snails around the world have right-coiled shells because of the intrinsic chirality in their genes. All the amino acids present in the human body exist in an enantiomerically pure state, except for glycine - the sole achiral amino acid.
13.3K
Dielectric Polarization in a Capacitor
4.7K
The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
4.7K
Chirality at Nitrogen, Phosphorus, and Sulfur
5.7K
Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...
5.7K
Potential Due to a Polarized Object
391
A neutral atom consists of a positively charged nucleus surrounded by a negatively charged electron cloud. When placed in an external electric field, the external electric force pulls the electrons and nucleus apart, opposite to the intrinsic attraction between the nucleus and the electrons. The opposing forces balance each other with a slight shift between the center of masses of the nucleus and the electron cloud, resulting in a polarized atom. On the other hand, a few molecules, like water,...
391
Induced Electric Dipoles
4.2K
A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium.
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
4.2K


