化非易燃电解质中的弱溶解化学在高压金属电池中实现稳定循环
Jingyu Guo1, Feng Hai1, Wenting Chen1
1Shaanxi Key Laboratory of Energy Chemical Process Intensification, School of Chemical Engineering and Technology, Xi'an Jiaotong University, No. 28 Xianning West Road, Xi'an, Shaanxi 710049, China.
ACS applied materials & interfaces
|June 7, 2024
概括
新的弱溶解电解质 (WSEs) 通过优化界面化学来增强高压电池. 这些先进的电解质可以使4.6V Liidiye NCM811电池的稳定循环,并提高在低温下性能.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 高压电池需要先进的电解质来提高能量密度.
- 当前的电解质在平衡金属兼容性,阴极稳定性和离子传输方面面临着挑战.
- 碳酸盐具有提高电解质性能的潜力.
研究的目的:
- 为高压电池设计新的弱溶解电解质 (WSEs).
- 为了改善接口化学和电化学稳定性.
- 为解决高能电池应用中电流电解质的局限性.
主要方法:
- 利用三种化线性碳酸盐来创建具有降低Li+亲和力和增强氧化稳定的WSEs.
- 使用低度盐 (1M) 来促进离子集群结构.
- 在Li Radix DCNCM811细胞中研究了界面化学和电化学性能.
主要成果:
- 实现了4.6V高电压光电池NCM811电池300个周期的稳定循环,保持了80%的容量.
- 由于较低的Li+溶解能量,在-20°C时表现出卓越的循环稳定性和低极化.
- 在WSEs中通过丰富的离子集群结构优化了界面化学.
结论:
- 弱溶解电解质 (WSEs) 为高压金属电池提供了一个有前途的解决方案.
- 开发的WSEs提高了稳定性和性能,特别是在高电压和低温度下.
- 这项研究推进了高特异能电池的电解质设计.
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