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Updated: Jun 24, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Published on: July 27, 2022

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激素连接物转移:由三元热力学控制的机制和反应性

Zuzanna Wojdyla1, Martin Srnec1

  • 1J. Heyrovský Institute of Physical Chemistry, The Czech Academy of Sciences Dolejškova 3 Prague 8 18223 Czech Republic martin.srnec@jh-inst.cas.cz.

Chemical science
|June 7, 2024
PubMed
概括

这项研究揭示了协调的离子电子转移 (cIET) 解释了激素连接体转移反应性. 一个热力学模型,考虑到对角线和离对角线的影响,准确地预测反应机制和特征.

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