一种从包括生物固体,堆肥和土壤在内的固体生物废物中提取微塑料的方法,通过μ-FTIR进行分析
Helena Ruffell1, Olga Pantos2, Brett Robinson1
1School of Physical and Chemical Sciences, University of Canterbury, Christchurch, New Zealand.
MethodsX
|June 7, 2024
概括
一种新方法有效地从生物废物 (如堆肥和土壤) 中提取微塑料. 这种技术确保了微塑料分析的高回收率,使用微里埃变换红外光谱法 (μ-FTIR).
科学领域:
- 环境科学 环境科学
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
背景情况:
- 从复杂的有机基质中提取微塑料的方法有限.
- 准确量化生物废物中微塑料的含量对于环境风险评估至关重要.
研究的目的:
- 开发和验证一种从固体生物废物中提取微塑料的方法.
- 为了使微塑料的光谱分析使用微里叶变换红外光谱学 (μ-FTIR).
主要方法:
- 固体生物废物经过了用铁 (II) 和过氧化进行湿过氧化 (WPO) 的消化.
- 使用超纯水和化 (NaI) 溶液在沉积物-微塑料隔离 (SMI) 装置中进行了序列密度分离.
- 该方法避免了磨削等破坏性过程,以保持微塑料的完整性.
主要成果:
- 微塑料的平均回收率为堆肥的92%,生物固体的95%,土壤的98%.
- 在WPO消化过程中,生物废物聚合物被有效地分解,释放被捕获的微塑料.
- 在SMI单元中的密度分离有助于有效地隔离微塑料.
结论:
- 开发的方法从各种固体生物废物中提供了高微塑料回收.
- 最少的加工步骤减少了提取过程中的污染和颗粒损失.
- 这种经过验证的方法适用于环境样本中的微塑料分析.
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