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Updated: Jun 24, 2025

HKUST-1 as a Heterogeneous Catalyst for the Synthesis of Vanillin
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金属有机框架支持的单双-铁氧化催化剂,用于选择性氧化到醇

Poorvi Gupta1, Naved Akhtar1, Wahida Begum1

  • 1Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India.

Inorganic chemistry
|June 8, 2024
PubMed
概括

一个新的金属有机框架催化剂,bpy-UiO-Fe(OH) 2,有效地将转化为,具有99%的选择性. 这种可持续的方法提供了一种更绿色的替代方案,用于烯合成的烯工艺.

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Simple aryl halides do not react with nucleophiles under normal conditions. However, the reaction can proceed under drastic conditions involving high temperatures and high pressure to give the substituted products. For example, chlorobenzene is converted to phenol using aqueous sodium hydroxide at 350 °C under high pressure by the Dow process. The reaction follows an elimination-addition mechanism involving a benzyne intermediate. Here, the chloride ion is...
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