一个基于MOF凝的分离器,用于抑制Li-O电池中的Redox介质穿2
Baoxing Wang1,2, Jiaheng Liu1, Chenghui Mao1
1Key Laboratory of Mesoscopic Chemistry of MOE, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, P. R. China.
Small (Weinheim an der Bergstrasse, Germany)
|June 11, 2024
概括
一种新型的金属有机框架凝 (MOF-gel) 分离器有效地防止了氧电池中的氧化还原介质穿. 这项创新显著提高了电池循环寿命和性能,解决了关键的降解问题.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 氧化还原介质 (RMs) 通过催化Li2O2反应来提高Li-O2电池的性能.
- 转移到阳极的RM导致退化,限制了电池的寿命.
研究的目的:
- 开发一种新型分离器来抑制RM穿.
- 为了提高Li-O2电池的循环稳定性和性能.
主要方法:
- 制造一个金属有机框架凝 (MOF-凝) 分离器.
- 将MOF凝分离器与Li-O2电池电池组合起来.
- 在各种电流密度 (0.5 A g-1 和 1.0 A g-1) 的电化学测试.
主要成果:
- MOF-凝分离器形成均的,密集的薄膜,有效地限制了RM的穿.
- 带有MOF凝分离器的-O2电池实现了0.5A g-1.0的410个周期的超长循环寿命.
- 在1.0A g-1下,性能显著改善 (约1.6倍),超电位降低.
结论:
- MOF-凝分离器是一种有前途的策略,可以减轻Li-O2电池中的RM穿.
- 这种方法提高了循环稳定性和电化学性能.
- 这些发现为未来的电池分离器设计和RM利用提供了指导.
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