空气稳定Na3.5C6O6作为纳米离子电池阴极中的补偿添加剂
Mengyan Cao1,2, Liang Xu3, Yujie Guo4
1Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing, 100190, China.
Small (Weinheim an der Bergstrasse, Germany)
|June 12, 2024
概括
一种新的牺牲添加剂Na3.5C6O6通过分解来补偿离子电池 (SIB) 中的损失,提供必要的离子,提高电池寿命和能量密度.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子电池 (SIB) 是由于低成本和的丰富性而有望用于静止存储.
- 对SIBs的主要挑战包括由于不可逆转的离子消耗和副作用导致的低能量密度和短寿命.
研究的目的:
- 引入Na3.5C6O6作为SIB中的阴极的空气稳定,高效的牺牲添加剂.
- 为了弥补电池运行期间的离子损失,并提高电化学性能.
主要方法:
- 用Na3.5C6O6添加剂对SIB的电化学表征.
- 物理表征技术,以分析添加剂的结构和分解.
- 密度函数理论 (DFT) 计算以阐明脱机制.
主要成果:
- Na3.5C6O6具有较低的脱潜力 (3.4-3.6 V) 和高的理论容量 (378 mAh g-1).
- 添加剂在初始充电过程中完全分解,提供没有惰性副产品的离子.
- 在Na2 / 3Ni1 / 3Mn1 / 3Ti1 / 3O2和其他以阴极为基础的SIB中观察到更好的电化学性能.
结论:
- Na3.5C6O6有效地弥补了的损失,提高了SIB的能量密度和寿命.
- 分解产物C6O6与碳酸盐电解质相容.
- 这项工作提出了推进高能量密度二次电池技术的新战略.
相关概念视频
Ionic Strength: Effects on Chemical Equilibria
1.4K
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
In this solution, the primary...
1.4K
Qualitative Analysis
22.2K
For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a series of selective precipitations with different chemical reagents, each reaction producing a characteristic precipitate for a specific group of cations. Metal ions within a group are further separated by varying the pH, heating the mixture to redissolve a precipitate, or adding other reagents to form complex ions.
For instance, group IV...
For instance, group IV...
22.2K
Ionic Bonds
118.3K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
118.3K
Ionic Compounds: Formulas and Nomenclature
66.8K
An element composed of atoms that readily lose electrons (a metal) can react with an element composed of atoms that readily gain electrons (a nonmetal) to produce ions through complete electron transfer. The compound formed by this transfer is stabilized by the electrostatic attractions (ionic bonds) between the oppositely charged ions.
66.8K
Ions as Acids and Bases
23.7K
Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
23.7K
Classification of Elements and Compounds
66.5K
Pure substances consist of only one type of matter. A pure substance can be an element or a compound. An element consists of only one type of atom, while a compound consists of two or more types of atoms held together by a chemical bond. Elements are classified as atomic or molecular based on the nature of their basic units.
Compounds are pure substances composed of two or more elements in fixed, definite proportions. Compounds are classified as ionic or molecular (covalent) based on the bonds...
Compounds are pure substances composed of two or more elements in fixed, definite proportions. Compounds are classified as ionic or molecular (covalent) based on the bonds...
66.5K


