Juan Manuel Moreno-Naranjo1, Francesco Furlan1, Jingxiang Wang2

  • 1Department of Chemistry, Molecular Sciences Research Hub, Imperial College London, White City Campus, London, W12 0BZ, UK.

概括

研究人员开发了一种新的方法来放大有机发光二极管 (OLED) 中的循环偏振光辐射. 这种技术增强了奇拉热激活延迟光 (TADF) 发射器,为先进的OLED技术铺平了道路.

相关概念视频

Photochemical Electrocyclic Reactions: Stereochemistry01:26

Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
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