研究石材回收成基于硫化的光的过程
Oleg A Medennikov1, Marina A Egorova1, Nina P Shabelskaya1
1Department of Ecology and Industrial Safety, Faculty of Technology, Platov South-Russian State Polytechnic University (NPI), Novocherkassk 346428, Russia.
Nanomaterials (Basel, Switzerland)
|June 13, 2024
概括
研究人员利用酸还原方法将石废料转化为发光的CaSO4/CaS复合材料. 最佳条件产生色辐射,证明了工业废物的可行回收方法.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 固态化学 固态化学
背景情况:
- 处理矿产原材料,特别是不合格的矿石和工业废物,如石膏,带来了重大的环境挑战.
- 石是酸生产的主要副产品,造成处理和环境问题.
研究的目的:
- 通过使用酸减少石膏来研究CaSO4/CaS复合材料的形成.
- 阐明复合结构形成的机制.
- 确定从石中生产发光材料的最佳条件.
主要方法:
- 在X射线衍射 (XRD) 中.
- 传输电子显微镜的使用
- 谢勒勒的方法 谢勒勒的方法
- 热重力测量分析 (TGA)
- 在FT-IR光谱学中使用.
主要成果:
- 提出了一个复合结构形成机制.
- 合成的材料表现出色发光 (500-750nm),量子输出率为0.17.
- 确定了最佳合成条件:1073K热处理,60分钟的保留时间和37%的减少剂分子分数.
- 偏离最佳条件降低了发光特性.
结论:
- 酸还原提供了一种回收化石材成发光CaSO4/CaS复合材料的方法.
- 该研究确定了最大化发光的最佳参数.
- 这些发现支持开发用于将化学工业废物转化为有价值的发光产品的技术.
相关概念视频
Photoluminescence: Applications
386
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
386
Photoluminescence: Fluorescence and Phosphorescence
2.0K
Photoluminescence is a process where a molecule absorbs light energy and re-emits it in the form of light. This phenomenon occurs when a substance absorbs photons, promoting its electrons to higher energy level excited states, followed by a relaxation process in which the electrons return to their original ground state energy levels and emit light. Photoluminescence is widely observed in various materials, including semiconductors, and organic and inorganic compounds.
A pair of electrons in a...
A pair of electrons in a...
2.0K
Gas Chromatography: Types of Detectors-II
359
In gas chromatography, different detectors are employed to meet specific analytical needs. These detectors are often categorized based on their detection mechanisms and the types of compounds they are best suited to analyze. Thermal Conductivity Detectors (TCD), Flame Ionization Detectors (FID), and Electron Capture Detectors (ECD) represent common categories, each with unique operating principles and applications. However, beyond these, several other detectors are designed for more specialized...
359
Washing, Drying, and Ignition of Precipitates
905
After filtration, the precipitate is washed to remove coprecipitated impurities and any remaining mother liquor. Colloidal precipitates, such as silver chloride, are washed with an electrolyte (such as dilute nitric acid) to prevent the peptization of the precipitate. In the case of slightly soluble precipitates, the wash solution contains a common ion to reduce solubility. Lead sulfate, which is slightly soluble in water, is washed with dilute sulfuric acid. Similarly, wash solutions may be...
905
Fluorescence and Phosphorescence: Instrumentation
577
Fluorometers and spectrofluorometers are two types of instruments used for measuring molecular fluorescence. These instruments differ in how they select excitation and emission wavelengths and the type of light sources they utilize. Fluorometers use absorption interference filters to choose excitation and emission wavelengths. The excitation source in a fluorometer is typically a low-pressure mercury vapor lamp that emits intense lines distributed throughout the ultraviolet and visible regions.
577
Flame Photometry: Lab
232
In a flame photometer, when a solution like potassium chloride is aspirated into the flame, the solvent evaporates, leaving behind dehydrated salt. This salt dissociates into free gaseous atoms in their ground state. Some of these atoms absorb energy from the flame, leading to their excitation. The excited atoms return to the ground state, emitting photons at characteristic wavelengths. Because only electronic transitions are involved, the resulting emission lines are very narrow. The intensity...
232


