具有增强的阴离子/阴离子还氧化剂的高能地球丰富阴极,用于可持续和持久的离子电池
Xu Zhang1,2, Wenhua Zuo3, Shiqi Liu1,2
1Institute of Advanced Battery Materials and Devices, College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, P. R. China.
Advanced materials (Deerfield Beach, Fla.)
|June 13, 2024
概括
这项研究引入了用于离子电池 (NIB) 的新型铁/基阴极. /联合剂稳定了结构,使可持续的储能能具有高容量和长周期寿命.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 可持续能源 可持续能源
背景情况:
- 多层铁/氧化物是可持续电池的有希望的阴极材料.
- 在这些阴极中,在高电压下稳定阴离子和阴离子氧化还原反应是具有挑战性的.
研究的目的:
- 为离子电池 (NIB) 设计一个稳定的P2-Na0.67Fe0.3Mn0.5Mg0.1Ti0.1O2阴极.
- 为了增强阴离子/阴离子氧化还原反应的可逆性,并抑制不必要的氧活动.
主要方法:
- 在高电压下进行电化学测试 (4.5V与金属相比).
- 先进的表征技术. 先进的表征技术.
- 计算建模. 计算建模.
主要成果:
- 在20 mA g-1下实现了≈210 mAh g-1的可逆容量.
- 经过300个循环以200 mA g-1.的300个循环后,表现出良好的循环稳定性,74%的容量保留.
- /联合兴奋剂稳定了结构,提高了氧化还原反应的可逆性.
结论:
- 在高电压和高温度下稳定Fe/Mn基层阴极时,Mg/Ti联合注至关重要.
- 这种方法抑制了不必要的氧气活动,导致可持续和长期的NIB.
相关概念视频
Batteries and Fuel Cells
27.3K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.3K
Voltaic/Galvanic Cells
57.0K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
57.0K
Electrolysis
26.3K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
26.3K
Electrodeposition
625
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Electrodeposition can...
625


