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Excess Pressure Inside a Drop and a Bubble01:13

Excess Pressure Inside a Drop and a Bubble

1.6K
The shape of a small drop of liquid can be considered spherical, neglecting the effect of gravity. This drop can further be considered as two equal hemispherical drops put together due to surface tension. The forces acting on the spherical drop are due to the pressure of the liquid inside the drop, the pressure due to air outside the drop, and the force due to the surface tension acting on the two hemispherical drops.
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Real Gases: Effects of Intermolecular Forces and Molecular Volume Deriving Van der Waals Equation04:01

Real Gases: Effects of Intermolecular Forces and Molecular Volume Deriving Van der Waals Equation

34.6K
Thus far, the ideal gas law, PV = nRT, has been applied to a variety of different types of problems, ranging from reaction stoichiometry and empirical and molecular formula problems to determining the density and molar mass of a gas. However, the behavior of a gas is often non-ideal, meaning that the observed relationships between its pressure, volume, and temperature are not accurately described by the gas laws. 
34.6K
Van der Waals Equation01:10

Van der Waals Equation

4.0K
The ideal gas law is an approximation that works well at high temperatures and low pressures. The van der Waals equation of state (named after the Dutch physicist Johannes van der Waals, 1837−1923) improves it by considering two factors.
First, the attractive forces between molecules, which are stronger at higher densities and reduce the pressure, are considered by adding to the pressure a term equal to the square of the molar density multiplied by a positive coefficient a. Second, the volume...
4.0K
pV-Diagrams01:18

pV-Diagrams

4.1K
The pV diagram, which is a graph of pressure versus volume of the gas under study, is helpful in describing certain aspects of the substance. When the substance behaves like an ideal gas, the ideal gas equation describes the relationship between its pressure and volume. On a pV diagram, it is common to plot an isotherm, which is a curve showing p as a function of V with the number of molecules and the temperature fixed. Then, for an ideal gas, the product of the pressure of the gas and its...
4.1K
Turbulent Flow: Problem Solving01:09

Turbulent Flow: Problem Solving

111
Carbonation is a process used to dissolve carbon dioxide gas in a liquid, commonly used in the production of carbonated beverages. Achieving efficient carbonation requires careful control of temperature, pressure, and flow conditions. By adjusting these parameters, carbonation efficiency can be maximized, producing a higher concentration of CO2 in the liquid.
Temperature is a key factor in CO2 solubility. In this case, the CO2 gas and the liquid are cooled to 20°C. Lower temperatures...
111
Vapor Pressure Lowering03:28

Vapor Pressure Lowering

26.5K
The equilibrium vapor pressure of a liquid is the pressure exerted by its gaseous phase when vaporization and condensation are occurring at equal rates:
 
Dissolving a nonvolatile substance in volatile liquid results in a lowering of the liquid’s vapor pressure. This phenomenon can be explained by considering the effect of added solute molecules on the liquid's vaporization and condensation processes. To vaporize, solvent molecules must be present at the surface of the solution....
26.5K

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气泡使得转移稳定的弹性毛囊系统中的体积负压缩能力.

Davide Caprini1, Francesco Battista2, Paweł Zajdel3

  • 1Center for Life Nano- & Neuro-Science, Istituto Italiano di Tecnologia, Viale Regina Elena 291, Rome, Italy.

Nature communications
|June 13, 2024
PubMed
概括

研究人员开发了一种新的方法来制造具有负压缩性的材料,使它们在压力下膨胀. 这一突破利用了毛细管力和泡形成在疏水性腔的应用在先进的材料和传感器.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 软物质物理学 软物质物理学
  • 材料机械学 材料机械学

背景情况:

  • 负压缩性,即材料在压缩下膨胀,是先进应用中罕见且非常受欢迎的特性.
  • 实现这种反直觉的行为通常需要破坏构成材料的平衡.
  • 诱导负压缩性的现有方法是有限的,通常是复杂的.

研究的目的:

  • 提出一个简单而有效的战略,以实现材料的负压缩性.
  • 为了证明这一策略在各种规模和材料类型中具有广泛的适用性.
  • 探索在需要可调节材料响应的领域的潜在应用.

主要方法:

  • 利用毛细管力在疏水性柔性腔内预压缩弹性材料.
  • 利用可逆的气泡形成和溶解作为控制预压缩的值现象.
  • 研究在不同压力下转移稳定的弹性毛囊系统的机械反应.

主要成果:

  • 在疏水的微孔材料,蛋白质和毫米尺寸的薄膜中证明了负压缩性.
  • 展示了毛细血管力和泡动力学诱导和控制这种独特性能的能力.
  • 证实了该现象在不同长度尺度上的有效性.

结论:

  • 拟议的弹性毛囊策略为设计负压缩性提供了一条简单的途径.
  • 这种方法是多用途的,适用于各种材料,从纳米级生物分子到宏观结构.
  • 这些发现为开发具有可调节灵敏度的新材料开辟了道路,用于传感器,多孔材料和其他领域的应用.