在水泥材料中的蛋白质被空气吸入的机制
Mohammad Sadegh Tale Masoule1, Elvis Baffoe1, Ali Ghahremaninezhad1
1Department of Civil and Architectural Engineering, University of Miami, Coral Gables, Florida 33146, United States.
Langmuir : the ACS journal of surfaces and colloids
|June 14, 2024
概括
蛋白质通过增加表面疏水性,主要是通过皮克林效应,从而提高空气空隙结构来增强水泥中的空气吸入. 高空气空隙多孔性是在中间糊口流速时实现的.
科学领域:
- 材料科学 材料科学 材料科学
- 土木工程 土木工程是指土木工程.
- 合体和表面化学
背景情况:
- 关于水泥材料中蛋白质吸附空气的特性存在有限的研究.
- 蛋白质诱导的空气携带和蛋白质-水泥相互作用的机制尚不清楚.
研究的目的:
- 研究蛋白质对影响水泥糊中空气吸入的因素的影响.
- 阐明在水泥系统中以蛋白质为媒介的空气吸入机制.
主要方法:
- 研究了13种不同的蛋白质,以评估不同蛋白质特性的影响.
- 分析了孔隙溶液的表面张力,水泥上的蛋白质吸附,糊的水化和新鲜糊的流量.
- 使用微计算机断层扫描 (micro-CT) 进行详细的空气空隙微结构分析.
主要成果:
- 蛋白质降低了孔隙溶液的表面张力,增加了糊的疏水性.
- 在水泥颗粒上的蛋白质吸附有很大差异,通过静电排斥和泡效应影响糊的流动.
- 微CT显示出不同的空气空隙微结构,取决于所使用的蛋白质.
- 在空气空隙孔隙度和表面疏水性之间发现了强烈的相关性;与表面张力存在弱相关性.
结论:
- 蛋白质在水泥糊中吸入空气的主要机制是皮克林效应,涉及水化水泥颗粒积聚在气泡上.
- 最佳的空气空隙多孔性是在新鲜糊口流量的中间范围内实现的.
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