聚烯微塑料的表面特征和吸附性质通过紫外线照射和自然老化
Lin Hao1, Hongzhu Ma1, Baoshan Xing2
1School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'An, Shaanxi 710119, PR China.
The Science of the total environment
|June 14, 2024
概括
这项研究研究了聚烯微塑料 (PP-MPs),比较原始,紫外线老化和自然老化的形式. 陈旧的PP-MP表现出改变的表面特征,影响了水晶紫色吸附,突出显示了微塑料污染的环境风险.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 分析化学 分析化学
背景情况:
- 微塑料 (MP) 是无处不在的环境污染物,但它们的行为仍然不太了解.
- 聚烯MPs (PP-MPs) 是常见的,它们的老化过程显著改变了表面特性.
研究的目的:
- 量化描述原始和老化的PP-MPs.
- 研究紫外线和自然老化对PP-MP表面特征的影响.
- 评估衰老对PP-MPs吸附水晶紫色 (CV) 的影响.
主要方法:
- 采用了富里埃红外光谱学,扫描电子显微镜,接触角度计,特定表面积分析和激光粒子分析.
- 碳烯指数 (CI) 被测量以量化衰老.
- 用水晶紫 (CV) 进行吸附实验.
主要成果:
- 紫外线老化PP-MP显示,随着暴露时间的增加,碳酸指数增加.
- 自然老化的PP-MPs产生了生物膜,并且具有最高的CI.
- 对CV的吸附能力在紫外线老化的PP-MP中增加,但在自然老化的PP-MP中降低,与水友性和CaCO3脱落有关.
- 吸附遵循PSO动力学和弗洛伊德利希等热量,表明多层,非均的吸附.
结论:
- 老化显著改变PP-MP表面特性和污染物的吸附行为.
- 碳酸在自然老化的PP-MPs的吸附特性中起作用.
- 了解这些变化对于评估微塑料的环境风险至关重要.
更多相关视频
05:05Quantification of Polybutylene Adipate Terephthalate-based Micro- and Nano-plastics from Soil Using Proton Nuclear Magnetic Resonance Spectroscopy
Published on: June 6, 2025
55
10:27The Evolution of Silica Nanoparticle-polyester Coatings on Surfaces Exposed to Sunlight
Published on: October 11, 2016
9.5K
相关概念视频
Types of Step-Growth Polymers: Polyesters
2.2K
The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
2.2K
Polymer Classification: Architecture
2.7K
Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
2.7K
Polymer Classification: Stereospecificity
2.4K
Polymerization generates chiral centers along the entire backbone of a polymer chain. Accordingly, the stereochemistry of the substituent group has a significant effect on polymer properties. Polymers formed from monosubstituted alkene monomers feature chiral carbons at every alternate position in the polymer backbone. Relative to the predominant orientation of substituents at the adjacent chiral carbons, the polymer can exist in three different configurations: isotactic, syndiotactic, and...
2.4K
