在滑动的DLCA模型中,分支结构的形成动态
Koichi Hirata1, Takeaki Araki1
1Division of Physics and Astronomy, Graduate School of Science, Kyoto University, Kitashirakawa, Sakyo, Kyoto 606-8502, Japan.
The Journal of chemical physics
|June 17, 2024
概括
体凝网络结构通过两条不同的路径形成,这取决于粒子度. 滑动扩散有限集群聚合 (DLCA) 揭示了体积分数如何决定分支和聚合路径.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 物理 物理学 物理
背景情况:
- 体凝是复杂的液体,在食品,药物和材料中具有应用.
- 了解它们的网络形成对于控制属性至关重要.
- 以前的模型往往过于简化了集群动态.
研究的目的:
- 通过数值研究合凝中的聚合动态和网络结构.
- 探索粒子体积分数对凝形成的影响.
- 阐明分支结构形成的不同途径.
主要方法:
- 在数值模拟中使用了滑动扩散有限集群聚合 (DLCA) 模型.
- 嵌入了灵活的结合角度,以允许集群变形.
- 采用减少网络方案进行定量分析.
主要成果:
- 根据体积分数 (φ) 确定了两个不同的分支结构形成路径.
- 低的φ (≤8%):集群变形先于透,然后是聚合和网络延长.
- 高φ (>8%):早期透导致同质分支,然后在老化过程中崩成更密集,异质的结构.
结论:
- 这项研究为体凝网络形成提供了新的视角.
- 这些发现为通过聚合途径控制凝弹性提供了见解.
- 灵活的DLCA模型准确地捕获了复杂的凝结构.
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