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无粘合剂交织的Si和MnO2复合电极用于高性能离子电池阳极
Zhaozhe Yu1, Tingfeng Guan1, Jiahui Liu1
1Guangxi Key Laboratory of Manufacturing Systems and Advanced Manufacturing Technology, Guilin University of Electronic Technology, Guilin 541004, PR China.
ACS applied materials & interfaces
|June 18, 2024
概括
无粘合剂的氧化- (Si-MO) 电极为离子电池提供了更好的循环稳定性. 这种新的设计减轻了体积膨胀,提高了商业应用的阳极性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 阳极由于其高容量而对离子电池 (LIB) 有前景,但由于体积扩张而受到影响.
- 无粘合剂电极可以提高导电性和粘合性,减轻的局限性.
研究的目的:
- 开发一种使用和二氧化 (Si-MO) 的无粘合剂交织电极.
- 为了提高LIBs的基阳极的循环稳定性和整体性能.
主要方法:
- 一个无粘合剂交织的Si-MO电极的制造.
- 电化学测试用于评估特定容量,循环稳定性和速率性能.
主要成果:
- Si-MO电极在420 mA g-1.1下显示了1300 mAh g-1的可逆特定容量.
- 观察到卓越的循环稳定性,在500个循环后保留了830 mAh g-1.
- 在200个周期内,在4200 mA g-1下达到837 mAh g-1的高速率性能.
结论:
- 无粘合剂的Si-MO电极有效地减轻了体积膨胀,提高了电化学性能.
- 这种方法在LIBs中为阳极的商业化提供了一个可行的战略.
相关概念视频
Ionic Bonding and Electron Transfer
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
Types of Reversible Electrodes
For electrode reversibility to be maintained, all the reactants and products involved in the half-reaction must be present at the electrode. There are several types of reversible electrodes (half-cells).In metal-metal-ion electrodes, a metal balances electrochemically with a solution of its own ions. Examples are Cu2+|Cu and Zn2+|Zn. Metals that react with the solvent, like group 1 and most group 2 metals, which react with water, and zinc, which reacts with aqueous acidic solutions, cannot be...

