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Updated: Jun 23, 2025

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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从二硫化碳裂中获得REMP的绑定基基烯

Vineet K Jakhar1, Yu-Hsuan Shen1, Rinku Yadav1

  • 1Department of Chemistry, Center for Catalysis, University of Florida, P.O. Box 117200, Gainesville, Florida 32611, United States.

Inorganic chemistry
|June 18, 2024
PubMed
概括

类类复合物与二硫化碳反应,形成新的硫化物复合物. 这些复合物经历转化,产生单体和二元物种,可用于环膨胀转化聚合.

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Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
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Diels–Alder reactions between cyclic dienes locked in an s-cis configuration and dienophiles yield bridged bicyclic products.
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