高合金及其与的亲和关系:从坎托尔到金组元素合金合金
Konstantin Glazyrin1, Kristina Spektor1, Maxim Bykov2
1Deutsches Elektronen-Synchrotron (DESY), Notkestr. 85, 22607, Hamburg, Germany.
Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|June 18, 2024
概括
高合金表现出显著的抗性,即使在极端压力下. 这一发现表明它们对于相关的工业应用,如储存和运输的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 金工业是金工业的一个方面.
背景情况:
- 高合金 (HEAs) 正因其独特的特性和潜在的应用而引起人们的注意.
- 高热与的相互作用,包括扩散和反应性,仍然是一个尚未探索的领域.
- 了解高温气体的气行为对于它们在气技术中的部署至关重要.
研究的目的:
- 研究在高合金中的亲和力,扩散和反应.
- 评估HEAs,包括Cantor和组金属 (PGM) 合金,在高压下对化物形成的抵抗力.
- 为了比较HEAs在不同传压介质 (Ne和H2) 中的行为.
主要方法:
- 在环境温度下使用钻石天细胞施加高压.
- 使用X射线衍射分析HEA样本中的结构变化.
- 结合过渡元素的HEAs的比较研究.
主要成果:
- 坎托尔合金和PGM合金都表现出对化物形成的异常抵抗力.
- 这种电阻甚至在明显超过传统工业条件的应力下也被观察到.
- 这些HEAs的性能与工业级铜合金的性能相当.
结论:
- 高合金在相关行业的应用方面显示出显著的前景.
- 它们对的异常耐用性表明它们适合用于运输和储存的组件.
- 根据这些发现,对气环境的高温电气进行进一步的研究是有必要的.
相关概念视频
Metallic Solids
18.4K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
18.4K
Reduction of Alkenes: Catalytic Hydrogenation
12.0K
Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
12.0K
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
3.3K
Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
3.3K
Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation
7.7K
Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
7.7K
Noble Gases
17.4K
The elements in group 18 are noble gases (helium, neon, argon, krypton, xenon, and radon). They earned the name “noble” because they were assumed to be nonreactive since they have filled valence shells. In 1962, Dr. Neil Bartlett at the University of British Columbia proved this assumption to be false.
17.4K
Properties of Organometallic Compounds
989
Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
989


