应变效应对弹性热塑性聚氨的介电性
Yubo Wang1,2,3, Huali Yang2,3, Yali Xie2,3
1School of Materials Science and Engineering, Shanghai Institute of Technology, Shanghai 201400, China.
Polymers
|June 19, 2024
概括
研究人员开发了一种装置,用于测量热塑性聚氨 (TPU) 在应力下的介电常数. 拉伸TPU显著降低了其介电性质,影响了灵活设备的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 介电材料 介电材料
背景情况:
- 像热塑性聚氨 (TPU) 这样的介电弹性体对于灵活和可拉伸的电子产品至关重要.
- 了解它们在变形时的介电行为对于稳定的设备运行至关重要.
研究的目的:
- 开发一种方法,以在现场测量压力下的TPU的介电常数.
- 研究TPU中应变,微观结构和介电性质之间的关系.
主要方法:
- 开发一种专门的装置,用于在拉伸应变下在现场测量介电常数.
- 利用里叶变换红外光谱学,X射线散射和原子力显微镜来分析微观结构变化.
主要成果:
- 在拉伸到400%的应变时,TPU的介电常数从8.02 ± 0.01下降到2.88 ± 0.25 (在1MHz).
- 微结构分析显示,极化硬域的密度和大小下降,以及分子链在应力下对齐.
结论:
- 该研究成功地证明了在压力下的TPU中介电常量演变的现场测量.
- 微观结构变化,包括域缩小和链条对齐,是导致介电常数观察到的下降的原因.
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