聚胺 6.6 的无水染色 6.6 的无水染色
1Textile Engineering Department, Bursa Uludag University, Bursa 16059, Türkiye.
Polymers
|June 19, 2024
概括
使用超临界二氧化碳 (scCO2) 的聚胺6.6无水染料为传统方法提供了一个环保的替代方案. 这项研究表明,scCO2染色有效地染色PA6.6织物,并改善了较大的染料的颜色强度.
科学领域:
- 织品化学 织品化学
- 绿色化学 绿色化学
- 材料科学 材料科学 材料科学
背景情况:
- 传统的织品染料严重依赖水,导致大量的水消耗和污染.
- 超临界二氧化碳 (scCO2) 为无水染色工艺提供了一个可行的,环保的替代方案.
- 聚胺 (PA) 纤维,包括聚胺6.6 (PA6.6),被广泛使用,可以用各种染料染色.
研究的目的:
- 通过使用超临界二氧化碳 (scCO2) 对聚胺6.6 (PA6.6) 的无水染料的可行性和有效性.
- 为了评估在scCO2环境中染色的PA6.6织物的染色性能和材料特性.
- 为了比较scCO2染色对环境的好处与传统的水性染色方法.
主要方法:
- 使用分散染料在scCO2中在100°C和220巴的温度下45分钟染色PA6.6织物.
- 测色分析 (K/S值) 用于评估颜色强度.
- 颜色强度测试,拉伸强度测量,扫描电子显微镜 (SEM) 和里埃变换红外光谱 (FTIR) 分析.
主要成果:
- 用scCO2染色的PA6.6织物表现出更高的色强度 (K/S值) 与更大的分子量染料.
- 与较大的颜色相比,中小尺寸的染料实现了类似的颜色强度.
- 保持了材料性能,如抗拉强度和结构完整性.
- FTIR分析证实了染料吸收和与PA6.6纤维的化学相互作用.
结论:
- 超临界二氧化碳染色是一种高效和环保的方法,用于染色聚胺6.6织物.
- 这种无水技术为传统染色提供了可持续的替代方案,减少了用水和污染.
- scCO2染色工艺允许良好的颜色发育,并保持织材料的物理和化学特性.
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