基于甲酸盐/酸和粉的两个非理想爆炸物的热危险分析
Jiahu Guo1, Xiaoping Chen1, Yanwu Yu2
1Emergency Management College, Chengdu University, Chengdu 610106, China.
Molecules (Basel, Switzerland)
|June 19, 2024
概括
这项研究分析了甲-和酸-爆炸物的热危害. 氨甲酸系统在各种氧气平衡条件下显示出更高的热稳定性和安全性.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 安全工程安全工程
背景情况:
- 民用爆炸事故造成大量伤亡和损失.
- 热刺激是爆炸性爆炸的一个关键因素.
- 在不同氧气平衡下,对非理想爆炸物的热危害的研究是有限的.
研究的目的:
- 研究非理想爆炸物的热危险特性.
- 分析氨甲酸和酸-系统的热力学参数.
- 评估氧气平衡对爆炸物热稳定的影响.
主要方法:
- 不同扫描热量计 (DSC) 分析.
- 爆炸性混合物的热力学分析.
- 评估峰值反应温度和激活能量.
主要成果:
- 在零氧平衡下,甲系统的峰值反应温度 (292°C) 和激活能量 (94.9kJ/mol) 比酸- (259°C,84.7kJ/mol) 高.
- 在负氧平衡下,这两种系统都表现出峰值激活能量 (AP-Al为104.2kJ/mol,AN-Al为86.2kJ/mol).
- 氨甲酸系统在相同的热刺激下显示出更高的安全性.
结论:
- 在类似的热条件下,甲-系统与酸-相比,提供了更高的安全性.
- 负氧平衡条件提高了研究的两个非理想爆炸系统的安全性.
- 了解在不同氧气平衡下发生的热危害对于改善爆炸物安全管理至关重要.
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