持续的细胞毒性和内分泌活动在第一个油砂终端坑湖
Ian G M Gault1, Chenxing Sun1, Jonathan W Martin2
1Division of Analytical and Environmental Toxicology, University of Alberta, Edmonton, Alberta T6G 2G3, Canada.
概括
湖泊中的老化油砂工艺受影响水 (OSPW) 由于稀释而减少毒性,而不是化学变化. 较老的OSPW中持续的毒性表明,其他有机化合物需要积极的治疗才能有效地修复.
科学领域:
- 环境科学 环境科学
- 毒理学 毒理学 毒理学
- 化学 化学 化学
背景情况:
- 油砂工艺影响水 (OSPW) 含有从矿开采中产生的持久性有机污染物.
- 在终端坑湖和基矿湖 (BML) 中老化OSPW是一个大规模的整治策略.
- 了解OSPW老化的长期有效性对于环境管理至关重要.
研究的目的:
- 在前五年评估OSPW老化在BML中的有效性.
- 评估老化OSPW的化学特征和毒理影响.
- 确定导致老年OSPW持续毒性的因素.
主要方法:
- 细胞毒性的实时细胞分析.
- 酵母雌激素和雄激素查 (YES/YAS) 对于内分泌干扰.
- 超高分辨率质谱仪用于化学分析.
- 在现场条件下经过不同时间的老化OSPW的分析.
主要成果:
- 细胞毒性每体积下降与OSPW老化在BML,归因于稀释.
- 每个提取物质质量的毒性强度和化学概况保持一致.
- 在20岁以上的OSPW中观察到持续的内分泌抗性和细胞毒性.
- 非酸性有机化合物在旧的OSPW中富含,与毒性相关.
结论:
- 稀释,而不是化学降解,主要是在初始老化过程中降低OSPW在BML中的毒性.
- 陈旧的OSPW可以保持显著的毒性,对水生生态系统构成风险.
- 积极的水处理方法可能是必要的,以加快OSPW排毒和防止遗留污染.
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