通过透试验和总含量测试,对天然聚合物的浸出行为进行调查
Martial Clavier1, Khadim Ndiaye2, Salima Aggoun2
1CY Cergy Paris Université, L2MGC, F-95000, Cergy, France. martial.clavier@cyu.fr.
概括
大多数天然聚合物是安全的,但有一些含有和等可浸元素,超过了安全限制. pH显著影响元素释放,而不是颗粒大小.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
背景情况:
- 泄漏试验监测建筑聚合物的环境行为,特别是废弃物中的替代材料.
- 自然聚合物研究较少,并且在欧盟中通常不受物质释放的监管.
- 这项研究的重点是自然聚合物的漏行为.
研究的目的:
- 为了研究天然聚合物的重金属,化物和硫酸盐的可浸含量.
- 为了将液含量与既定的值进行比较.
- 确定谷粒大小和pH等因素对浸出的影响,并确定释放机制.
主要方法:
- 上游透试验 (EN 16637-3) 用于评估可漏物质.
- 总元素含量通过酸性消化来确定.
- 使用EN 16637-3 - 附件D分析了主要的释放机制,考虑pH值,电导率和液含量.
主要成果:
- 在19种测试的天然聚合物中,只有3种 (NS2,NG1,NG8) 超过了特定元素 (As,Zn) 的值.
- 鉴定出pH值是一个比谷粒大小更重要的影响水的因素.
- 样本NS2中的 (As) 和 (Mo) 显示出高透性,表明一种可溶化学形式.
结论:
- 天然聚合物一般表现出低漏,很少超过监管限制.
- pH 是控制自然聚合物中可浸元素释放的关键因素.
- 对大量存在的元素来说,准确确定释放机制是可行的,但对微量元素来说是有限的.
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