在铁电极化切换过程中单晶Mn化BiFeO3薄膜中的中间多域状态
Seiji Nakashima1, Koji Kimura2,3,4, Naohisa Happo5
1Department of Electronics and Computer Science, Graduate School of Engineering, University of Hyogo, Himeji, Hyogo, 671-2201, Japan. nakashima@eng.u-hyogo.ac.jp.
Scientific reports
|June 21, 2024
概括
将电场应用于Mn-doped BiFeO3薄膜会通过铁弹性域切换诱导晶体学倾斜. 这种原子位移为设计先进的压电和铁电装置提供了洞察力.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 晶体学 晶体学是指结晶学.
背景情况:
- 用添加的比斯穆特铁 (BiFeO3) 薄膜具有复杂的铁电和磁性.
- 了解域切换机制对于优化多铁材料应用至关重要.
- 电场引起的铁电材料的结构变化是设备功能的关键.
研究的目的:
- 在应用电场下的单域Mn-doped BiFeO3薄膜中研究铁弹性域切换的动态.
- 阐明晶体学倾斜,域切换和原子移位之间的关系.
- 探索逆压电效应在推动结构变化的潜力.
主要方法:
- 在现场光X射线诱导的Kossel线图案测量使用同步辐射.
- 在现场逆X射线光全息 (XFH) 实验.
- 电场沿着 [110]pc 方向在 (001) pc 导向的薄膜中应用.
主要成果:
- 在电场应用过程中观察一个中间的多域状态.
- (hh0) pc平面的显著晶体学倾斜 (1.78°) 归因于109°铁弹性域切换.
- 通过反向压电效应引起的原子位移的确认.
结论:
- 在BFMO薄膜中,铁弹性域切换通过一个中间的多域状态进行.
- 反向压电效应是观察到的原子移位和晶体学倾斜的原因.
- 结果为下一代压电和铁电材料和设备的合理设计提供了关键的见解.
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