用β-环氧胺修饰的GO超膜具有增强的防物质,用于净化水
Meng Zhu1, Hao Liang2, Xiaobo Gong1
1Key Laboratory of the Evaluation and Monitoring of Southwest Land Resources (Ministry of Education), College of Chemistry and Materials Science, Sichuan Environmental Protection Key Laboratory of Persistent Pollutant Wastewater Treatment, Sichuan Normal University, Chengdu, Sichuan, 610068, China.
Environmental research
|June 22, 2024
概括
碳甲基改性石墨烯氧化物纳米颗粒显著增强聚硫膜,改善油砂工艺净水的水流和防性质.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 混合矩阵膜 (MMM) 对于水处理至关重要.
- 聚二硫 (PES) 膜往往患有不良的水友性和污染.
- 提高膜性能需要有效的添加剂策略.
研究的目的:
- 为了研究碳素甲基改性β-环氧化和石墨烯氧化物 (CMβ-CD/GO) 纳米颗粒对PES膜特性的影响.
- 为了评估修改后的膜的水友性,流量,形态和防性能.
- 评估处理油砂处理过程水和油性废水的潜力.
主要方法:
- 制造CMCD@GO纳米颗粒通过修改石墨烯氧化物与氧甲基β-环氧.
- 将CMCD@GO纳米粒子纳入聚乙硫矩阵,以创建MMM (MCDGO-x).
- 膜性质的表征,包括水接触角度,水流,形态和纳酸 (NA) 排斥.
主要成果:
- CMCD@GO纳米粒子改善了PES膜的水友性 (WCA <51.5°) 和水流量 (32.6 L m−2h−1).
- 修改后的膜表现出更薄的活性层和类似手指的结构,具有稳定的纳米粒子分散.
- MCDGO-x膜显示出优异的NA排斥 (>93.2%) 和改善的流量回收率 (79.3%) 后的污染周期,表明增强的抗污染特性.
结论:
- CMβ-CD和GO的组合有效地提高了PES超膜的性能.
- 开发的MMM显示了油砂工艺水净化和油性废水处理的巨大潜力.
- 这项研究强调了一种有前途的方法,用于创建具有卓越流量和防能力的先进膜.
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