多功能离子液体凝由动态共价键和微相分离结构形成
Zeyu Zhang1, Xin Zhao1, Xing Song2
1Key Laboratory of Bio-based Material Science & Technology (Northeast Forestry University) Ministry of Education, School of Materials Science and Engineering, Northeast Forestry University, Harbin 150040, China. renshixue@nefu.edu.cn.
离子液体凝 (DI-PR) 已开发出具有快速自我愈合和高强度的凝. 作为交叉连接剂的鲁提高了材料的性能,使它们适合用于抗腐蚀涂层.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
背景情况:
- 在离子液体凝中同时实现快速自我愈合和高性是一个重大挑战.
- 现有的材料往往会损害一种材料的另一种特性.
研究的目的:
- 开发具有增强自愈和性的新型离子液体凝 (DI-PR).
- 探索使用鲁丁作为"刚性-柔性"交联剂来改善材料性能.
主要方法:
- 使用聚卡普罗拉克二醇,异相二酸盐,二甲基乙烯氧胺和常规的DI-PR离子液体凝的制备.
- 机械性能的表征,包括抗拉强度,破裂时的延长和性.
- 评估自愈速率,温度稳定性和对钢材的附着性.
主要成果:
- DI-PR凝具有很高的抗拉强度 (16.5 MPa),破裂时的延长 (1132.6%),以及性 (52.6 MJ m-3).
- 该材料表现出快速的自我愈合 (在室温下92%在1秒内反弹) 和从-50°C到140°C的功能稳定性.
- 观察到对钢材的特殊粘附性 (>2000 J m-2),表明它适合用于保护性涂层.
结论:
- 开发的DI-PR离子液体凝成功地将快速自我愈合与高性相结合.
- 鲁独特的"刚性-柔性"结构提供了一种新的方法,通过协同作用来增强软材料的性.
- 这些凝对于在苛刻的环境中作为管道的防腐涂层的应用具有前景.
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