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相关概念视频

Ion Exchange01:17

Ion Exchange

574
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
574
Intermolecular Forces03:13

Intermolecular Forces

58.2K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
58.2K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

17.1K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
17.1K
Ionic Bonds00:42

Ionic Bonds

118.2K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
118.2K
Aqueous Solutions and Heats of Hydration02:42

Aqueous Solutions and Heats of Hydration

14.6K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
14.6K

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相关实验视频

Updated: Jun 23, 2025

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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Published on: March 24, 2018

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多功能离子液体凝由动态共价键和微相分离结构形成.

Zeyu Zhang1, Xin Zhao1, Xing Song2

  • 1Key Laboratory of Bio-based Material Science & Technology (Northeast Forestry University) Ministry of Education, School of Materials Science and Engineering, Northeast Forestry University, Harbin 150040, China. renshixue@nefu.edu.cn.

Materials horizons
|June 24, 2024
PubMed
概括

离子液体凝 (DI-PR) 已开发出具有快速自我愈合和高强度的凝. 作为交叉连接剂的鲁提高了材料的性能,使它们适合用于抗腐蚀涂层.

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Thermal Scanning Conductometry TSC as a General Method for Studying and Controlling the Phase Behavior of Conductive Physical Gels
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科学领域:

  • 材料科学 材料科学 材料科学
  • 聚合物化学 聚合物化学

背景情况:

  • 在离子液体凝中同时实现快速自我愈合和高性是一个重大挑战.
  • 现有的材料往往会损害一种材料的另一种特性.

研究的目的:

  • 开发具有增强自愈和性的新型离子液体凝 (DI-PR).
  • 探索使用鲁丁作为"刚性-柔性"交联剂来改善材料性能.

主要方法:

  • 使用聚卡普罗拉克二醇,异相二酸盐,二甲基乙烯氧胺和常规的DI-PR离子液体凝的制备.
  • 机械性能的表征,包括抗拉强度,破裂时的延长和性.
  • 评估自愈速率,温度稳定性和对钢材的附着性.

主要成果:

  • DI-PR凝具有很高的抗拉强度 (16.5 MPa),破裂时的延长 (1132.6%),以及性 (52.6 MJ m-3).
  • 该材料表现出快速的自我愈合 (在室温下92%在1秒内反弹) 和从-50°C到140°C的功能稳定性.
  • 观察到对钢材的特殊粘附性 (>2000 J m-2),表明它适合用于保护性涂层.

结论:

  • 开发的DI-PR离子液体凝成功地将快速自我愈合与高性相结合.
  • 鲁独特的"刚性-柔性"结构提供了一种新的方法,通过协同作用来增强软材料的性.
  • 这些凝对于在苛刻的环境中作为管道的防腐涂层的应用具有前景.